For the given reactions, A + B $$\to$$ Products, following data were obtained
(a) Write the rate law expression
(b) Find the rate constant

Find the equilibrium constant for the reaction,
In²⁺ + Cu²⁺ $$\to$$ In³⁺ + Cu⁺ at 298 K
given
$$E_{C{u^{2 + }}/C{u^ + }}^o$$ = 0.15 V; $$E_{l{n^{2 + }}/l{n^ + }}^o$$ = -0.40 V; $$E_{l{n^{3 + }}/l{n^ + }}^o$$ = -0.42 V;

1.22 g of benzoic acid is dissolved in 100 g of acetone and 100 g of benzene separately. Boiling point of the solution in acetone increases by 0.17 ^oC, while that in the benzene increases by 0.13^oC; K_b for acetone and benzene is 1.7 K kg mol^-1 and 2.6 K kg mol^-1. Find molecular weight of the benzoic acid in two cases and justify your answer.

A compound AB has rock salt type structure. The formula weight of AB is 6.023 Y amu, and the closest A - B distance is Y^1/3 nm, where Y is an arbitrary number
(a) Find the density of the lattice
(b) If the density of lattice is found to be 20 kg m^-3, then predict the type of defect

Draw the structure of XeF₄ and OSF₄ according to VSEPR theory clearly indicating the state of hybridisation of the central atom and lone pair of electrons (if any) on the central atom.

Arrange the following :

In the decreasing order of the O - O bond length present in them

O₂, KO₂ and O₂[AsF₄]

A ball of mass 100 g is moving with 100 ms^-1. Find it's wavelength.

(a) The Schrodinger wave equation for hydrogen atom is

$$$\psi = {1 \over {4\sqrt {2\pi } }}{\left( {{1 \over {{a_0}}}} \right)^{3/2}}\left( {2 - {{{r_0}} \over {{a_0}}}} \right){e^{ - {r_0}/{a_0}}}$$$
Where a₀ is Bohr's radius. If the radial node in 2s be at r₀, then find r₀ in terms of a₀.

(b) A baseball having mass 100 g moves with velocity 100 m/s. Determine the value of wavelength of baseball.

Find the equation of plane passing through $$(1, 1, 1)$$ & parallel to the lines $${L_1},{L_2}$$ having direction ratios $$(1,0,-1),(1,-1,0).$$ Find the volume of tetrahedron formed by origin and the points where these planes intersect the coordinate axes.

$${P_1}$$ and $${P_2}$$ are planes passing through origin. $${L_1}$$ and $${L_2}$$ are two line on $${P_1}$$ and $${P_2}$$ respectively such that their intersection is origin. Show that there exists points $$A, B, C,$$ whose permutation $$A',B',C'$$ can be chosen such that (i) $$A$$ is on $${L_1},$$ $$B$$ on $${P_1}$$ but not on $${L_1}$$ and $$C$$ not on $${P_1}$$ (ii) $$A'$$ is on $${L_2},$$ $$B'$$ on $${P_2}$$ but not on $${L_2}$$ and $$C'$$ not on $${P_2}$$

If $$\overrightarrow a ,\overrightarrow b ,\overrightarrow c $$ and $$\overrightarrow d $$ are distinct vectors such that
$$\,\overrightarrow a \times \overrightarrow c = \overrightarrow b \times \overrightarrow d $$ and $$\overrightarrow a \times \overrightarrow b = \overrightarrow c \times \overrightarrow d \,.$$ Prove that
$$\left( {\overrightarrow a - \overrightarrow d } \right).\left( {\overrightarrow b - \overrightarrow c } \right) \ne 0\,\,i.e.\,\,\,\overrightarrow a .\overrightarrow b + \overrightarrow d .\overrightarrow c \ne \overrightarrow d .\overrightarrow b + \overrightarrow a .\overrightarrow c $$

Find the centre and radius of circle given by $$\,\left| {{{z - \alpha } \over {z - \beta }}} \right| = k,k \ne 1\,$$

where, $${\rm{z = x + iy, }}\alpha {\rm{ = }}\,{\alpha _1}{\rm{ + i}}{\alpha _2}{\rm{,}}\,\beta = {\beta _1}{\rm{ + i}}{\beta _2}{\rm{ }}$$

A parallelopiped $$'S'$$ has base points $$A, B, C$$ and $$D$$ and upper face points $$A',$$ $$B',$$ $$C'$$ and $$D'.$$ This parallelopiped is compressed by upper face $$A'B'C'D'$$ to form a new parallelopiped $$'T'$$ having upper face points $$A'',B'',C''$$ and $$D''.$$ Volume of parallelopiped $$T$$ is $$90$$ percent of the volume of parallelopiped $$S.$$ Prove that the locus of $$'A''',$$ is a plane.

A box contains $$12$$ red and $$6$$ white balls. Balls are drawn from the box one at a time without replacement. If in $$6$$ draws there are at least $$4$$ white balls, find the probability that exactly one white is drawn in the next two draws. (binomial coefficients can be left as such)

$$A$$ and $$B$$ are two independent events. $$C$$ is even in which exactly one of $$A$$ or $$B$$ occurs. Prove that $$P\left( C \right) \ge P\left( {A \cup B} \right)P\left( {\overline A \cap \overline B } \right)$$

A curve $$'C''$$ passes through $$(2,0)$$ and the slope at $$(x,y|)$$ as $$\,{{{{\left( {x + 1} \right)}^2} + \left( {y - 3} \right)} \over {x + 3}}$$. Find the equation of the curve. Find the area bounded by curve and $$x$$-axis in fourth quadrant.

Find the value of $$\int\limits_{ - \pi /3}^{\pi /3} {{{\pi + 4{x^3}} \over {2 - \cos \left( {\left| x \right| + {\pi \over 3}} \right)}}dx} $$

If $$y\left( x \right) = \int\limits_{{x^2}/16}^{{x^2}} {{{\cos x\cos \sqrt \theta } \over {1 + {{\sin }^2}\sqrt \theta }}d\theta ,} $$ then find $${{dy} \over {dx}}$$ at $$x = \pi $$

Prove that for $$x \in \left[ {0,{\pi \over 2}} \right],$$ $$\sin x + 2x \ge {{3x\left( {x + 1} \right)} \over \pi }$$. Explain
the identity if any used in the proof.

Using Rolle's theorem, prove that there is at least one root
in $$\left( {{{45}^{1/100}},46} \right)$$ of the polynomial
$$P\left( x \right) = 51{x^{101}} - 2323{\left( x \right)^{100}} - 45x + 1035$$.

Tangent is drawn to parabola $${y^2} - 2y - 4x + 5 = 0$$ at a point $$P$$ which cuts the directrix at the point $$Q$$. $$A$$ point $$R$$ is such that it divides $$QP$$ externally in the ratio $$1/2:1$$. Find the locus of point $$R$$

Find the equation of circle touching the line 2x + 3y + 1 = 0 at (1, -1) and cutting orthogonally the circle having line segment joining (0, 3) and (- 2, -1) as diameter.

Prove by permulation or otherwise $${{({n^2})!} \over {{{(n!)}^n}}}$$ is an integer $$(n \in {1^ + })$$.

If $$a,\,b,c$$ are positive real numbers. Then prove that $$${\left( {a + 1} \right)^7}{\left( {b + 1} \right)^7}{\left( {c + 1} \right)^7} > {7^7}\,{a^4}{b^4}{c^4}$$$

A screw gauge having 100 equal divisions and a pitch of length 1 mm is used to measure the diameter of a wire of length 5.6 cm. The main scale reading is 1mm and 47^th circular division coincides with the main scale. Find the curved surface area of wire in cm² to appropriate significant figures. ( use $$\pi = {{22} \over 7}$$ )

In Searle's experiment, which is used to find Young's Modulus of elasticity, the diameter of experimental wire is D = 0.05 cm ( measured by a scale of least count 0.001 cm ) and length is L = 110 cm ( measured by a scale of least count 0.1 cm ). A weight of 50 N causes an extension of X = 0.125 cm (measured by a micrometer of least count 0.001 cm ). Find maximum possible error in the value of Young's modulus. Screw gauge and and meter scale are free from error.