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Paper was held on Wed, Apr 11, 1984 9:00 AM
Chemistry
1
Many elements have non-integral atomic masses because:
2
2.68 $$\times$$ 10-3 moles of a solution containing an ion An+ require 1.61 $$\times$$ 10-3 moles of $$MnO_4^-$$ for the oxidation of An+ to $$AO_3^-$$ in acid medium. What is the value of n?
3
Correct set of four quantum numbers for the valence (outermost) electron of rubidium (Z = 37) is
4
The increasing order (lowest first) for the values of e/m (charges/mass) for electron (e), proton (p), neutron (n) and alpha particle ($$\alpha$$) is:
5
Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon?
6
An isotone of $${}_{32}^{76}Ge$$ is
7
When alpha particles are sent through a thin metal foil, most of them go straight through the foil because
8
The electron energy in hydrogen atom is given by E = (-21.7 $$\times$$ 10-12)/n2 ergs. Calculate the energy required to remove an electron completely from the n = 2 orbit. What is the longest wavelength (in cm) of light that can be used to cause this transition?
9
On hybridization of one s and one p orbitals we get:
10
The total energy of one mole of an ideal monatomic gas at 27o is _______ calories.
11
Cp - Cv for an ideal gas is _______
12
Equal weights of methane and hydrogen are mixed in an empty container at 25oC. The fraction of the total pressure exerted by hydrogen is
13
The hydration energy of Mg++ is larger than that of:
14
The IUPAC name of the compound having the formula is :


15
When 16.8 g of white solid X were heated, 4.4 g of acid gas A, that turned lime water milky was driven off together with 1.8 g of a gas B which condensed to a colourless liquid.
The solid that remained, Y, dissolved in water to give an alkaline solution, which with excess barium chloride solution gave a white precipitate Z. The precipitate efferversced with acid giving off carbon dioxide. Identify A, B and Y and write down the equation for the thermal decomposition of X.
Mathematics
1
Given a function $$f(x)$$ such that
(i) it is integrable over every interval on the real line and
(ii) $$f(t+x)=f(x),$$ for every $$x$$ and a real $$t$$, then show that
the integral $$\int\limits_a^{a + 1} {f\,\,\left( x \right)} \,dx$$ is independent of a.
(i) it is integrable over every interval on the real line and
(ii) $$f(t+x)=f(x),$$ for every $$x$$ and a real $$t$$, then show that
the integral $$\int\limits_a^{a + 1} {f\,\,\left( x \right)} \,dx$$ is independent of a.
2
Find the area of the region bounded by the $$x$$-axis and the curves defined by
$$$y = \tan x, - {\pi \over 3} \le x \le {\pi \over 3};\,\,y = \cot x,{\pi \over 6} \le x \le {{3\pi } \over 2}$$$
3
Three identical dice are rolled. The probability that the same number will appear on each of them is
4
A box contains $$24$$ identical balls of which $$12$$ are white and $$12$$ are black. The balls are drawn at random from the box one at a time with replacement. The probability that a white ball is drawn for the $$4$$th time on the $$7$$th draw is
5
If $$M$$ and $$N$$ are any two events, the probability that exactly one of them occurs is
6
In a certain city only two newspapers $$A$$ and $$B$$ are published, it is known that $$25$$% of the city population reads $$A$$ and $$20$$% reads $$B$$ while $$8$$% reads both $$A$$ and $$B$$. It is also known that $$30$$% of those who read $$A$$ but not $$B$$ look into advertisements and $$40$$% of those who read $$B$$ but not $$A$$ look into advertisements while $$50$$% of those who read both $$A$$ and $$B$$ look into advertisements. What is the percentage of the population that reads an advertisement?
7
$$A, B, C$$ and $$D,$$ are four points in a plane with position vectors $$a, b, c$$ and $$d$$ respectively such that
$$$\left( {\overrightarrow a - \overrightarrow d } \right)\left( {\overrightarrow b - \overrightarrow c } \right) = \left( {\overrightarrow b - \overrightarrow d } \right)\left( {\overrightarrow c - \overrightarrow a } \right) = 0$$$
The point $$D,$$ then, is the ................ of the triangle $$ABC.$$
8
The points with position vectors $$a+b,$$ $$a-b,$$ and $$a+kb$$ are collinear for all real values of $$k.$$
9
If the complex numbers, $${Z_1},{Z_2}$$ and $${Z_3}$$ represent the vertics of an equilateral triangle such that
$$\left| {{Z_1}} \right| = \left| {{Z_2}} \right| = \left| {{Z_3}} \right|$$ then $${Z_1} + {Z_2} + {Z_3} = 0.$$
$$\left| {{Z_1}} \right| = \left| {{Z_2}} \right| = \left| {{Z_3}} \right|$$ then $${Z_1} + {Z_2} + {Z_3} = 0.$$
10
Evaluate the following $$\int {{{dx} \over {{x^2}{{\left( {{x^4} + 1} \right)}^{3/4}}}}} $$
11
There exists a value of $$\theta $$ between 0 and $$2\pi $$ that satisfies the equation $$\,\,{\sin ^4}\theta - 2{\sin ^2}\theta - 1 = 0.$$
12
$$\left( {1 + \cos {\pi \over 8}} \right)\left( {1 + \cos {{3\pi } \over 8}} \right)\left( {1 + \cos {{5\pi } \over 8}} \right)\left( {1 + \cos {{7\pi } \over 8}} \right)$$ is equal to
13
If 1, $${{a_1}}$$, $${{a_2}}$$......,$${a_{n - 1}}$$ are the n roots of unity, then show that (1- $${{a_1}}$$) (1- $${{a_2}}$$) (1- $${{a_3}}$$) ....$$(1 - \,a{ - _{n - 1}}) = n$$
14
Find the values of $$x \in \left( { - \pi , + \pi } \right)$$ which satisfy the equation $${g^{(1 + \left| {\cos x} \right| + \left| {{{\cos }^2}x} \right| + \left| {{{\cos }^3}x} \right| + ...)}} = {4^3}$$
15
For real $$x$$, the function $$\,{{\left( {x - a} \right)\left( {x - b} \right)} \over {x - c}}$$ will assume all real values provided
16
If the product of the roots of the equation $$\,{x^2} - 3\,k\,x + 2\,{e^{2lnk}} - 1 = 0\,\,\,\,is\,7$$, then the roots are real for k = .................................
17
If a < b < c < d, then the roots of the equation (x - a) (x - c) + 2 ( x - b) (x - d) = 0 are real and distinct.
18
The equation $$x - {2 \over {x - 1}} = 1 - {2 \over {x - 1}}$$ has
19
If $$\,{a^2} + {b^2} + {c^2} = 1$$, then ab + bc + ca lies in the interval
20
The side AB, BC and CA of a triangle ABC have 3, 4 and 5 interior points respectively on them. The number of triangles that can be constructed using these interior points as vertices is .......................
21
If $$p$$ be a natural number then prove that $${p^{n + 1}} + {\left( {p + 1} \right)^{2n - 1}}$$ is divisible by $${p^2} + p + 1$$ for every positive integer $$n$$.
22
Given $${s_n} = 1 + q + {q^2} + ...... + {q^2};$$
$${S_n} = 1 + {{q + 1} \over 2} + {\left( {{{q + 1} \over 2}} \right)^2} + ........ + {\left( {{{q + 1} \over 2}} \right)^n}\,\,\,,q \ne 1$$
Prove that $${}^{n + 1}{C_1} + {}^{n + 1}{C_2}{s_1} + {}^{n + 1}{C_3}{s_2} + ..... + {}^{n + 1}{C_n}{s_n} = {2^n}{S_n}$$
$${S_n} = 1 + {{q + 1} \over 2} + {\left( {{{q + 1} \over 2}} \right)^2} + ........ + {\left( {{{q + 1} \over 2}} \right)^n}\,\,\,,q \ne 1$$
Prove that $${}^{n + 1}{C_1} + {}^{n + 1}{C_2}{s_1} + {}^{n + 1}{C_3}{s_2} + ..... + {}^{n + 1}{C_n}{s_n} = {2^n}{S_n}$$
23
The sum of integers from 1 to 100 that are divisible by 2 or 5 is ............
24
If $$a > 0,\,b > 0$$ and $$\,c > 0,$$ prove that $$\,c > 0,$$ prove that $$\left( {a + b + c} \right)\left( {{1 \over a} + {1 \over b} + {1 \over c}} \right) \ge 9$$
25
If $$n$$ is a natural number such that
$$n = {p_1}{}^{{\alpha _1}}{p_2}{}^{{\alpha _2}}.{p_3}{}^{{\alpha _3}}........{p_k}{}^{{\alpha _k}}$$ and $${p_1},{p_2},\,\,......,\,{p_k}$$ are distinct primes, then show that $$In$$ $$n \ge k$$ $$in$$ 2
$$n = {p_1}{}^{{\alpha _1}}{p_2}{}^{{\alpha _2}}.{p_3}{}^{{\alpha _3}}........{p_k}{}^{{\alpha _k}}$$ and $${p_1},{p_2},\,\,......,\,{p_k}$$ are distinct primes, then show that $$In$$ $$n \ge k$$ $$in$$ 2
26
If $$a,\,b$$ and $$c$$ are in A.P., then the straight line $$ax + by + c = 0$$ will always pass through a fixed point whose coordinates are ...............
27
Two equal sides of an isosceles triangle are given by the equations $$7x - y + 3 = 0$$ and $$x + y - 3 = 0$$ and its thirds side passes through the point $$(1, -10)$$. Determine the equation of the third side.
28
The lines 3x - 4y + 4 = 0 and 6x - 8y - 7 = 0 are tangents to the same circle. The radius of this circle is ........................................
29
The locus of the mid-point of a chord of the circle $${x^2} + {y^2} = 4$$ which subtends a right angle at the origin is
30
The abscissa of the two points A and B are the roots of the equation $${x^2}\, + \,2ax\, - {b^2} = 0$$ and their ordinates are the roots of the equation $${x^2}\, + \,2px\, - {q^2} = 0$$. Find the equation and the radius of the circle with AB as diameter.
31
If $$\alpha $$ be a repeated root of a quadratic equation $$f(x)=0$$ and $$A(x), B(x)$$ and $$C(x)$$ be polynomials of degree $$3$$, $$4$$ and $$5$$ respectively,
then show that $$\left| {\matrix{ {A\left( x \right)} & {B\left( x \right)} & {C\left( x \right)} \cr {A\left( \alpha \right)} & {B\left( \alpha \right)} & {C\left( \alpha \right)} \cr {A'\left( \alpha \right)} & {B'\left( \alpha \right)} & {C'\left( \alpha \right)} \cr } } \right|$$ is
divisible by $$f(x)$$, where prime denotes the derivatives.
then show that $$\left| {\matrix{ {A\left( x \right)} & {B\left( x \right)} & {C\left( x \right)} \cr {A\left( \alpha \right)} & {B\left( \alpha \right)} & {C\left( \alpha \right)} \cr {A'\left( \alpha \right)} & {B'\left( \alpha \right)} & {C'\left( \alpha \right)} \cr } } \right|$$ is
divisible by $$f(x)$$, where prime denotes the derivatives.
32
For a triangle $$ABC$$ it is given that $$\cos A + \cos B + \cos C = {3 \over 2}$$. Prove that the triangle is equilateral.
33
With usual notation, if in a triangle $$ABC$$;
$${{b + c} \over {11}} = {{c + a} \over {12}} = {{a + b} \over {13}}$$ then prove that $${{\cos A} \over 7} = {{\cos B} \over {19}} = {{\cos C} \over {25}}$$.
$${{b + c} \over {11}} = {{c + a} \over {12}} = {{a + b} \over {13}}$$ then prove that $${{\cos A} \over 7} = {{\cos B} \over {19}} = {{\cos C} \over {25}}$$.
34
The numerical value of $$\tan \left\{ {2{{\tan }^{ - 1}}\left( {{1 \over 5}} \right) - {\pi \over 4}} \right\}$$ is equal to __________
35
For $$0 < a < x,$$ the minimum value of the function $$lo{g_a}x + {\log _x}a$$ is $$2$$.
36
Evaluate the following $$\int\limits_0^{{1 \over 2}} {{{x{{\sin }^{ - 1}}x} \over {\sqrt {1 - {x^2}} }}dx} $$
Physics
1
Four person K, L, M, N are initially at the four corners of a square of side d. Each person now moves with a uniform speed v in such a way that K always moves directly towards L, L directly towards M, M directly towards N, and N directly towards K. The four person will meet at a time _____________.
2
A projectile fired from the ground follows a parabolic path. The speed of the projectile is minimum at the top of its path.
3
A block of mass 1 kg lies on a horizontal surface in a truck. The coefficient of static friction between the block and the surface is 0.6. If the acceleration of the truck is 5 m/s2, the frictional force acting on the block is _________ newtons.
4
A simple pendulum with a bob of mass m swings with an angular amplitude of $$40^\circ $$. When its angular displacement is $$20^\circ $$, the tension in the string is greater than mg cos$$20^\circ $$.
5
A body is moved along a straight line by a machine delivering constant power. The distance moved by the body in the time t is proportional to