A $$300 \mathrm{~mL}$$ bottle of soft drink has $$0.2 ~\mathrm{M}~ \mathrm{CO}_{2}$$ dissolved in it. Assuming $$\mathrm{CO}_{2}$$ behaves as an ideal gas, the volume of the dissolved $$\mathrm{CO}_{2}$$ at $$\mathrm{STP}$$ is ____________ $$\mathrm{mL}$$. (Nearest integer)

Given : At STP, molar volume of an ideal gas is $$22.7 \mathrm{~L} \mathrm{~mol}^{-1}$$

The number of statement/s, which are correct with respect to the compression of carbon dioxide from point (a) in the Andrews isotherm from the following is ___________

A. Carbon dioxide remains as a gas upto point (b)

B. Liquid carbon dioxide appears at point (c)

C. Liquid and gaseous carbon dioxide coexist between points (b) and (c)

D. As the volume decreases from (b) and (c), the amount of liquid decreases

'x' g of molecular oxygen $$\left(\mathrm{O}_{2}\right)$$ is mixed with $$200 \mathrm{~g}$$ of neon (Ne). The total pressure of the non-reactive mixture of $$\mathrm{O}_{2}$$ and Ne in the cylinder is 25 bar. The partial pressure of Ne is 20 bar at the same temperature and volume. The value of 'x' is _________.

[Given: Molar mass of $$\mathrm{O}_{2}=32 \mathrm{~g} \mathrm{~mol}^{-1}$$.

Molar mass of $$\mathrm{Ne}=20 \mathrm{~g} \mathrm{~mol}^{-1}$$]

For a real gas at $$25^{\circ} \mathrm{C}$$ temperature and high pressure (99 bar) the value of compressibility factor is 2, so the value of Vander Waal's constant 'b' should be __________ $$\times 10^{-2} \mathrm{~L} \mathrm{~mol}^{-1}$$ (Nearest integer)

(Given $$\mathrm{R}=0.083 \mathrm{~L}$$ bar $$\mathrm{K}^{-1} \mathrm{~mol}^{-1}$$)