JEE Advanced 2025 Paper 1 Online | Compounds Containing Nitrogen Question 2 | Chemistry

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

List–I	List–II
(P) Stephen reaction	(1) $$ \text { Toluene } \xrightarrow{\begin{array}{l} \text { (i) } \mathrm{CrO}_2 \mathrm{Cl}_2 / \mathrm{CS}_2 \\ \text { (ii) } \mathrm{H}_3 \mathrm{O}^{+} \end{array}} $$
(Q) Sandmeyer reaction	(2) $$ \text { Benzoic acid } \xrightarrow{\substack{\text { (i) } \mathrm{PCl}_5 \\ \text { (ii) } \mathrm{NH}_3 \\ \text { (iii) } \mathrm{P}_4 \mathrm{O}_{10}, \Delta}} $$
(R) Hoffmann bromamide degradation reaction	(3) $$ \text { Nitrobenzene } \xrightarrow{\begin{array}{l} \text { (i) } \mathrm{Fe}, \mathrm{HCl} \\ \text { (ii) } \mathrm{HCl}, \mathrm{NaNO}_2 \\ (273-278 \mathrm{~K}), \mathrm{H}_2 \mathrm{O} \end{array}} $$
(S) Cannizzaro reaction	(4) $$ \text { Toluene } \xrightarrow{\begin{array}{ll} \text { (i) } \mathrm{Cl}_2 / \mathrm{h\nu}, \mathrm{H}_2 \mathrm{O} \\ \text { (ii) Tollen's reagent } \\ \text { (iii) } \mathrm{SO}_2 \mathrm{Cl}_2 \\ \text { (iv) } \mathrm{NH}_3 \end{array}} $$
	(5) $$ \text { Aniline } \xrightarrow{\begin{array}{l} \text { (i) }\left(\mathrm{CH}_3 \mathrm{CO}\right)_2 \mathrm{O}, \text { Pyridine } \\ \text { (ii) } \mathrm{HNO}_3, \mathrm{H}_2 \mathrm{SO}_4, 288 \mathrm{~K} \\ \text { (iii) aq. } \mathrm{NaOH} \end{array}} $$

P → 2; Q → 4; R → 1; S → 3

P → 2; Q → 3; R → 4; S → 1

P → 5; Q → 3; R → 4; S → 2

P → 5; Q → 4; R → 2; S → 1

JEE Advanced 2024 Paper 1 Online

MCQ (Single Correct Answer)

-1

List-I contains various reaction sequences and List-II contains different phenolic compounds. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

List-I	List-II

P-2, Q-3, R-4, S-5

P-2, Q-3, R-5, S-1

P-3, Q-5, R-4, S-1

P-3, Q-2, R-5, S-4

JEE Advanced 2022 Paper 1 Online

MCQ (Single Correct Answer)

-1

Match the compounds in LIST-I with the observations in LIST-II, and choose the correct option.

List-I	List-II
(I) Aniline	(P) Sodium fusion extract of the compound on boiling with $\mathrm{FeSO}_{4}$, followed by acidification with conc. $\mathrm{H}_{2} \mathrm{SO}_{4}$, gives Prussian blue color.
(II) $o$-Cresol	(Q) Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
(III) Cysteine	(R) Addition of the compound to a saturated solution of $\mathrm{NaHCO}_{3}$ results in effervescence.
(IV) Caprolactam	(S) The compound reacts with bromine water to give a white precipitate.
	(T) Treating the compound with neutral $\mathrm{FeCl}_{3}$ solution produces violet color.

$\mathrm{I} \rightarrow \mathrm{P}, \mathrm{Q}$; II $\rightarrow \mathrm{S} ; \mathrm{III} \rightarrow \mathrm{Q}, \mathrm{R}$; IV $\rightarrow \mathrm{P}$

$\mathrm{I} \rightarrow \mathrm{P}$; II $\rightarrow \mathrm{R}$, $\mathrm{S}$; III $\rightarrow \mathrm{R}$; $\mathrm{IV} \rightarrow \mathrm{Q}, \mathrm{S}$

$\mathrm{I} \rightarrow \mathrm{Q}, \mathrm{S}$; II $\rightarrow \mathrm{P}, \mathrm{T}$; III $\rightarrow \mathrm{P}$; IV $\rightarrow \mathrm{S}$

$\mathrm{I} \rightarrow \mathrm{P}$, S; II $\rightarrow \mathrm{T}$; III $\rightarrow \mathrm{Q}, \mathrm{R}$; $\mathrm{IV} \rightarrow \mathrm{P}$

JEE Advanced 2017 Paper 2 Offline

MCQ (Single Correct Answer)

-0.75

The major product of the following reaction is

JEE Advanced 2017 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 32 English

JEE Advanced 2017 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 32 English Option 1

JEE Advanced 2017 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 32 English Option 2

JEE Advanced 2017 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 32 English Option 3

JEE Advanced 2017 Paper 2 Offline Chemistry - Compounds Containing Nitrogen Question 32 English Option 4

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