If the vectors $a \hat{\mathbf{i}}+\mathbf{j}+3 \hat{\mathbf{k}}, 4 \hat{\mathbf{i}}+5 \hat{\mathbf{j}}+\hat{\mathbf{k}}$ and $4 \hat{\mathbf{i}}+2 \hat{\mathbf{j}}+6 \hat{\mathbf{k}}$ are coplanar, then $a$ is equal to

The values of $x$ for which the angle between the vectors $x^2 \hat{\mathbf{i}}+2 x \hat{\mathbf{j}}+\hat{\mathbf{k}}$ and $\hat{\mathbf{i}}-2 \hat{\mathbf{j}}+x \hat{\mathbf{k}}$ is obtuse lie in the interval