Chemical Equilibrium
Practice Questions
MCQ (Single Correct Answer)
1
At $300 \mathrm{~K}, K_C$ for the reaction. $$ A_2 B_2(g) \rightleftharpoons A_2(g)+B_2(g) $$ is $100 \mathrm{~mol} \mathrm{~L}^{-1}$, What is its $K_p$ (in atm ) at the same temperature ? $\left(R=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\right)$
AP EAPCET 2024 - 23th May Morning Shift
2

At equilibrium of the reaction,

$$ A_2(g)+B_2(g) \rightleftharpoons 2 A B(g) $$

The concentrations of $A_2, B_2$ and $A B$ respectively are $15 \times 10^{-3} \mathrm{M}, 2.1 \times 10^{-3} \mathrm{M}$, and $1.4 \times 10^{-3} \mathrm{M}$ in a sealed vessel at 800 K . What will be $K_p$ for the decomposition of $A B$ at same temperature ?

AP EAPCET 2024 - 22th May Morning Shift
3
15 moles of $\mathrm{H}_2$ and 5.2 moles of $\mathrm{I}_2$ are mixed and allowed to attain equilibrium at 773 K . At equilibrium, the number of moles of HI is found to be 10 . The equilibrium constant for the dissociation of HI is
AP EAPCET 2024 - 21th May Evening Shift
4
$K_C$ for the reaction,
$A_2(g) \stackrel{T(\mathrm{~K})}{\rightleftharpoons} B_2(\mathrm{~g})$
is 39.0. In a closed one litre flask, one mole of $A_2(g)$ was heated to $T(\mathrm{~K})$. What are the concentrations of $A_2(g)$ and $B_2(g)$ (in mol L ${ }^{-1}$ ) respectively at equilibrium?
AP EAPCET 2024 - 21th May Morning Shift
5

At $T(\mathrm{~K})$, the equilibrium constant for the reaction $\mathrm{H}_2(g)+\mathrm{Br}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{HBr}(\mathrm{g})$

is $1.6 \times 10^5$. If 10 bar of HBr is introduced into a sealed vessel at $T(\mathrm{~K})$, the equilibrium pressure of HBr (in bar) is approximately

AP EAPCET 2024 - 20th May Evening Shift
6
$K_C$ for the reaction, $A_2(g) \stackrel{T(\mathrm{~K})}{\rightleftharpoons} B_2(g)$ is 99.0 . In a 1 L closed flask two moles of $B_2(g)$ is heated to $T(\mathrm{~K})$. What is the concentration of $B_2(g)\left(\right.$ in $\left.\mathrm{mol} \mathrm{L}^{-1}\right)$ at equilibrium?
AP EAPCET 2024 - 20th May Morning Shift
7

$K_{\mathrm{c}}$ for the following reaction is 99.0

$$ A_2(g) \stackrel{T(K)}{\rightleftharpoons} B_2(g) $$

In a one litre flask, 2 moles of $A_2$ was heated to $T(\mathrm{~K})$ and the above equilibrium is reached. The concentration at equilibrium of $A_2$ and $B_2$ are $C_1\left(A_2\right)$ and $C_2\left(B_2\right)$ respectively. Now, one mole of $A_2$ was added to flask and heated to $T(\mathrm{~K})$ to established the equilibrium again. The concentration of $A_2$ and $B_2$ are $C_3\left(A_2\right)$ and $C_4\left(B_2\right)$ respectively. what is the value of $C_3\left(A_2\right)$ in $\mathrm{mol} \mathrm{L}^{-1}$ ?

AP EAPCET 2024 - 19th May Evening Shift
8
At $T(\mathrm{~K}), K_c$ for the reaction $A_2(g) \rightleftharpoons B_2(g)$ is 99.0 . Two moles of $A_2(s)$ was heated to $T(\mathrm{~K})$ in a 1 L . closed flask to reach the above equilibrium. What are the concentrations (in mol $\mathrm{L}^{-1}$ ) of $A_2(g)$ and $B_2(g)$ respectively at equilibrium?
AP EAPCET 2024 - 18th May Morning Shift
9
At $27^{\circ} \mathrm{C}$, the degree of dissociation of weak acid ( $\mathrm{H} A$ ) in its 0.5 M aqueous solution is $1 \%$. Its $K_e$, value is approximately
AP EAPCET 2024 - 18th May Morning Shift
10

At 500 K , for the reaction $$\mathrm{N}_2(\mathrm{~g})+3 \mathrm{H}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NH}_3(\mathrm{~g})$$, the $$K_p$$ is $$0.036 \mathrm{~atm}^{-2}$$. What is its $$K_C$$ in $$\mathrm{L}^2 \mathrm{~mol}^{-1}$$ ? $$\left(R=0.082 \mathrm{~L}^2\right.$$ atom $$\left.\mathrm{mol}^{-1} \mathrm{~K}^{-1}\right)$$.

AP EAPCET 2022 - 5th July Morning Shift
11

The formation of ammonia from its constituent elements is an exothermic reaction. The effect of increased temperature on the reaction equilibrium is

AP EAPCET 2022 - 4th July Morning Shift
12

At $$60^{\circ} \mathrm{C}$$, dinitrogen tetroxide is dissociated. Find it's standard free energy change at this temperature and one atmosphere. [Given $$\log 1.33=0.1239$$]

AP EAPCET 2021 - 20th August Morning Shift
13

Le-Chatelier's principle is not applicable to

AP EAPCET 2021 - 20th August Morning Shift
14

Using the data provided, find the value of equilibrium constant for the following reaction at $$298 \mathrm{~K}$$ and $$1 \mathrm{~atm}$$ pressure.

$$\begin{aligned} \mathrm{NO}(g)+\frac{1}{2} \mathrm{O}_2(g) \rightleftharpoons & \mathrm{NO}_2(g) \\ \Delta_f H \mathrm{Y}[\mathrm{NO}(g)] & =90.4 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \Delta_f H \mathrm{Y}\left[\mathrm{NO}_2(g)\right] & =32.48 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \Delta S Y a t ~298 \mathrm{~K} & =-70.8 \mathrm{~JK}^{-1} \mathrm{~mol}^{-1} \end{aligned}$$

$$[\operatorname{antilog}(0.50)=3162 \text { ] }$$

AP EAPCET 2021 - 19th August Evening Shift
15

Standard entropies of $$X_2, Y_2$$ and $$X Y_3$$ are 60, 40 and $$50 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$$ respectively. At what temperature, the following reaction will be at equilibrium? [given: $$\Delta H \Upsilon=-30 \mathrm{~kJ}$$]

$$\frac{1}{2} X_2+\frac{3}{2} Y_2 \rightleftharpoons X Y_3$$

AP EAPCET 2021 - 19th August Morning Shift
16

For the reaction $$\mathrm{SO}_2(g)+\frac{1}{2} \mathrm{O}_2(g) \rightleftharpoons \mathrm{SO}_3(g)$$, the percentage yield of product at different pressure is shown in the figure. Then, which among the following is true?

AP EAPCET 2021 - 19th August Morning Shift Chemistry - Chemical Equilibrium Question 17 English

AP EAPCET 2021 - 19th August Morning Shift
17

Which among the following denotes the correct relationship between $$K_p$$ and $$K_c$$ for the reaction, $$2 A(g) \rightleftharpoons B(g)+C(g)$$

AP EAPCET 2021 - 19th August Morning Shift