Electrochemistry
Practice Questions
MCQ (Single Correct Answer)
1
The pH of 0.5 L of 1.0 M NaCl solution after .electrolysis for 965 s using 5.0 A current is,
BITSAT 2024
2
Calculate the molarity of a solution containing 5 g of NaOH dissolved in the product of $ \mathrm{H}_{2}-\mathrm{O}_{2} $ fuel cell operated at 1 A current for 595.1 hours. (Assume $ \mathrm{F}=96500 \mathrm{C} / \mathrm{mol} $ of electron and molecular weight of NaOH as $ 40 \mathrm{~g} \mathrm{~mol}^{-1} $ ).
BITSAT 2024
3

The equilibrium constant of the reaction

$$A(s)+2 B^{+}(a q) \rightleftharpoons A^{2+}(a q)+2 B(s)$$

$$E_{\text {cell }}^{\circ}=0.0295 \mathrm{~V} \text { is } \quad\left[\frac{2.303 R T}{F}=0.059\right]$$

BITSAT 2023
4

Using the standard electrode potential, find out the pair between which redox reaction is not feasible.

E$$^\Theta $$ values Fe3+ / Fe2+ = + 0.77; I2 / I$$-$$ = + 0.54 Cu2+ / Cu = + 0.34; Ag+ / Ag = 0.80 V

BITSAT 2022
5

The molar conductivities of KCl, NaCl and KNO3 are 152, 128 and 111 S cm2 mol$$-$$1 respectively. What is the molar conductivity of NaNO3?

BITSAT 2021
6

The approximate time duration in hours to electroplate 30 g of calcium from molten calcium chloride using a current of 5 A is (Atomic mass of Ca = 40)

BITSAT 2021
7

Given, the reduction potential of Na+, Mg2+, Al3+ and Ag+ as $$E_{N{a^ + }/Na}^o$$ = $$-$$ 2.17 V; $$E_{M{g^{2 + }}/Mg}^o$$ = $$-$$ 2.37 V; $$E_{A{g^ + }/Ag}^o$$ = $$-$$ 0.08 V.

The least stable oxide is

BITSAT 2021
8

A solution of copper sulphate is electrolyzed between copper electrodes by a current of 10.0A passing for one hour. Which of the following statements is correct regarding the changes occur at the electrodes and in the solution?

BITSAT 2020