1
The radius of third orbit of hydrogen atom is $R \mathrm{pm}$. The radius of second orbit of $\mathrm{He}^{+}$ion (in pm is)
2
The threshold frequency of a metal is $10^{15} \mathrm{~s}^{-1}$. The ratio of maximum kinetic energies of the photoelectrons, when the metal is made to strike with radiations of frequencies $1.5 \times 10^{15} \mathrm{~s}^{-1}$ and $2.0 \times 10^{15} \mathrm{~s}^{-1}$ respectively is
3
Consider the following.
(I) The order of first ionisation enthalpy of first three elements of 3rd period is $\mathrm{Mg}>\mathrm{Al}>\mathrm{Na}$.
(II) The element with electronegativity of 3.5 is chlorine.
(III) The order of sizes of ions $\mathrm{Mg}^{2+}, \mathrm{Na}^{+}, \mathrm{F}^{-}$and $\mathrm{O}^{2-}$ is $\mathrm{Mg}^{2+}<\mathrm{Na}^{+}<\mathrm{F}^{-}<\mathrm{O}^{2-}$.
(IV) The IUPAC name of the element with atomic number 106 is bohrium.
The correct statements are
4
In which of the following set of molecules the hybridisation of central atoms is different?
5
At 300 K and 760 torr pressure, the density of a mixture of He and $\mathrm{O}_2$ gases is $0.543 \mathrm{gL}^{-1}$. The mass percent of oxygen approximately is
$$
\left(R=0.0821 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right)
$$
6
The equivalent weight of which of the following is maximum?
(Given : atomic weights $\mathrm{Na}=23, \mathrm{Mn}=55$,
$$
\mathrm{Cr}=52, \mathrm{~K}=39, \mathrm{O}=16, \mathrm{C}=12)
$$
7
If 2.5 moles of an ideal gas at a certain temperature are allowed to expand isothermally and reversibly from an initial volume of $2 \mathrm{dm}^3$ to $20 \mathrm{dm}^3$, the work done by the gas is -16.5 kJ . The temperature (in K ) of the gas is (Round off to the nearest value) ( $R=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ )
8
A solution is prepared by mixing 10 mL of 1.0 M acetic acid and 20 mL of 0.5 M sodium acetate and diluted to 100 mL . If the $\mathrm{p} K_a$ of acetic acid is 4.76, then the pH of the solution is
9
Consider the following statements about the hydrides.
(I) Sodium hydride with water liberates oxygen gas.
(II) Methane, silane are examples of electron precise hydrides.
(III) Ammonia and water molecules are examples of electron deficient hydrides.
(IV) Hydrides of beryllium and magnesium are polymeric in structure.
The correct statements are
10
The nitrate of which of the following metals does mot liberate $\mathrm{NO}_2$ gas on heating?
12
What are the correct statements about the elements of group 13 given below?
(I) The stability of +1 oxidation state follows the order $\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}$.
(II) Boron has the lowest melting point and boiling point as it is a non-metal.
(III) Boron shows a maximum covalency of 4 in its compounds.
(IV) The order of atomic radius is $\mathrm{Ga}>\mathrm{Al}>\mathrm{In}$.
(V) Aluminium is passive to concentrated nitric acid.
13
Assertion (A) Graphite is used as a dry lubricant in machines which run at high temperatures.
Reason ( $\mathbf{R}$ ) The layers of graphite slip one over the other when pressure is applied.
The correct option among the following is
14
The correct IUPAC name of the compound given under is

15
At $T(\mathrm{~K})$, copper (atomic mass $=63.5 \mathrm{u}$ ) has fce structure with an edge length of $x \AA$. The density of copper (in $\mathrm{g} \mathrm{cm}^{-3}$ ) at that temperature approximately is $\left(N_A=6.0 \times 10^{23} \mathrm{~mol}^{-1}\right)$
16
The vapour pressure of a pure liquid $A$ is 70 torr at 300 K . It forms an ideal solution with another liquid $B$. The mole fraction of $B$ is 0.2 and total vapour pressure of the solution is 84 torr at the same temperature. The vapour pressure of pure liquid $B$ (in torr) is
17
The electrode potential of chlorine electrode is maximum, when the concentration of chloride ion in the solution (in $\mathrm{mol} \mathrm{L}^{-1}$ ) is $X$. What is the value of $X$ ?
18
If benzene diazonium chloride undergoes first order decomposition at $T(\mathrm{~K})$ with a rate constant of $6.93 \times 10^{-2} \mathrm{~min}^{-1}$, the time for completion of $90 \%$ of the reaction (in min ) is (nearest integer) $(\log 2=0.30$, $\log 3=0.477$ )
19
Identify the factors which favour the physical adsorption from the following
(I) High surface area
(II) Low temperatures
(III) High temperatures
(IV) Low pressures
(V) High pressures
20
Sphalerite, siderite and malachite are the ores of metals $X, Y$ and $Z$. The atomic numbers of them are respectively
21
Consider the reaction,
$$ \mathrm{P}_4+3 \mathrm{NaOH}+3 \mathrm{H}_2 \mathrm{O} \longrightarrow Q+3 \mathrm{NaH}_2 \mathrm{PO}_2 $$
Identify the reaction in which $Q$ is not the product. (equations are not balanced)
22
The oxidation state of sulphur atoms and numbers of $\mathrm{S}-\mathrm{OH}$ bonds in peroxydisulphuric acid are respectively
23
Identify the correct statements from the following.
(I) Au is soluble in aqua regia but not Pt .
(II) Among the oxoacids of chlorine highest oxidation state possible for chlorine is +7 .
(III) Among the hydrogen halides lowest boiling point is for HCl .
(IV) The order of stability of oxides of halogens is $\mathrm{Cl}>\mathrm{Br}>\mathrm{I}$.
24
$$
\underset{(1: 20)}{\mathrm{Xe}(g)+\mathrm{F}_2(\mathrm{~g}) \xrightarrow[60-70 \text { bar }]{573 \mathrm{~K}} X(\mathrm{~s})}
$$
$$
X+\mathrm{H}_2 \mathrm{O} \longrightarrow Y+\mathrm{HF}, X+3 \mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{Z}+\mathrm{HF}
$$
The correct statements regarding $Y$ and $Z$ are
(I) $Y$ has square pyramidal geometry.
(II) $Y$ has linear geometry.
(III) Z has $3 \sigma, 3 \pi$ bonds and 1 lone pair of electrons on the central atom.
(IV) Z has tetrahedral geometry.
25
The number $f$-electrons in +3 oxidation state of gadolinium $(Z=64)$ is $x$ and in +2 oxidation state of ytterbium $(Z=70)$ is $y$. The sum of $x$ and $y$ is
26
Table
Match the following.

The correct answer is
27
Amongst the following, how many of them come under the category of elastomers?
Natural rubber, polyethene, vulcanized rubber, bakelite, polyvinylchloride, buna-N, nylon-6, neoprene
28
Which of the following is the incorrect statement about maltose?
29
Which of the following is not correctly matched?
30
Consider the following reaction sequence

The correct statements about $Z$ are
I. It gives yellow precipitate with $\mathrm{I}_2$ and NaOH solution.
II. It undergoes disproportionation reaction in the presence of concentrated NaOH solution.
III. It undergoes Wolff-Kishner reduction.
IV, If forms red precipitate with Fehling's reagent.
31

Conversion of $A$ to $B$ is an example of the reaction
32
In which of the following hyperconjugation is not possible?
33

The functional groups in $X$ and $Y$ are respectively.
34
Identify the major product $B$ in the given sequence of reactions.

35
Match the following.

The correct answer is Table
36
Which of the following is least reactive towards $\mathrm{S}_{\mathrm{N}} 2$ reaction?
37
Phenol is mainly manufactured from a compound $X$ by subjecting it to oxidation in air followed by treating with dilute acid. Identify the compound $X$.
38
Identify $A$ and $B$ from the following reactions

39
What are the products $X$ and $Y$ respectively in the reactions I and II?

40
Identify the product ' $Y$ ' in the following sequence of reactions
