JEE Main 2024 (Online) 27th January Morning Shift | JEE Main Paper Questions with Solutions

$$\begin{aligned} & \mathrm{P}=\left[\mathrm{FeF}_6\right]^{3-} \\ & \mathrm{Q}=\left[\mathrm{V}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} \\ & \mathrm{R}=\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} \end{aligned}$$

The correct order of the complex ions, according to their spin only magnetic moment values (in B.M.) is :

Choose the polar molecule from the following:

Given below are two statements :

Statement (I) : The $$4 \mathrm{f}$$ and $$5 \mathrm{f}$$ - series of elements are placed separately in the Periodic table to preserve the principle of classification.

Statement (II) : S-block elements can be found in pure form in nature.

In the light of the above statements, choose the most appropriate answer from the options given below :

Given below are two statements :

Statement (I) : p-nitrophenol is more acidic than m-nitrophenol and o-nitrophenol.

Statement (II) : Ethanol will give immediate turbidity with Lucas reagent.

In the light of the above statements, choose the correct answer from the options given below :

The ascending order of acidity of $$-\mathrm{OH}$$ group in the following compounds is :

Choose the correct answer from the options given below:

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Melting point of Boron (2453 K) is unusually high in group 13 elements.

Reason (R) : Solid Boron has very strong crystalline lattice.

In the light of the above statements, choose the most appropriate answer from the options given below ;

Cyclohexene

is ________ type of an organic compound.

Yellow compound of lead chromate gets dissolved on treatment with hot $$\mathrm{NaOH}$$ solution. The product of lead formed is a :

Given below are two statements :

Statement (I) : Aqueous solution of ammonium carbonate is basic.

Statement (II) : Acidic/basic nature of salt solution of a salt of weak acid and weak base depends on $$K_a$$ and $$K_b$$ value of acid and the base forming it.

In the light of the above statements, choose the most appropriate answer from the options given below :

IUPAC name of following compound (P) is:

$$\mathrm{NaCl}$$ reacts with conc. $$\mathrm{H}_2 \mathrm{SO}_4$$ and $$\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$$ to give reddish fumes (B), which react with $$\mathrm{NaOH}$$ to give yellow solution (C). (B) and (C) respectively are ;

The correct statement regarding nucleophilic substitution reaction in a chiral alkyl halide is ;

The electronic configuration for Neodymium is:

[Atomic Number for Neodymium 60]

The mass of silver (Molar mass of $$\mathrm{Ag}: 108 \mathrm{~gmol}^{-1}$$ ) displaced by a quantity of electricity which displaces $$5600 \mathrm{~mL}$$ of $$\mathrm{O}_2$$ at S.T.P. will be ______ g.

Consider the following data for the given reaction

$$2 \mathrm{HI}_{(\mathrm{g})} \rightarrow \mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})}$$

The order of the reaction is _________.

Mass of methane required to produce $$22 \mathrm{~g}$$ of $$\mathrm{CO}_2$$ after complete combustion is _______ g.

(Given Molar mass in g mol-1 $$\mathrm{C}=12.0$$, $$\mathrm{H}=1.0$$, $$\mathrm{O}=16.0)$$

If three moles of an ideal gas at $$300 \mathrm{~K}$$ expand isothermally from $$30 \mathrm{~dm}^3$$ to $$45 \mathrm{~dm}^3$$ against a constant opposing pressure of $$80 \mathrm{~kPa}$$, then the amount of heat transferred is _______ J.

3-Methylhex-2-ene on reaction with $$\mathrm{HBr}$$ in presence of peroxide forms an addition product (A). The number of possible stereoisomers for '$$\mathrm{A}$$' is ________.

Among the given organic compounds, the total number of aromatic compounds is

Among the following, total number of meta directing functional groups is (Integer based)

$$-\mathrm{OCH}_3,-\mathrm{NO}_2,-\mathrm{CN},-\mathrm{CH}_3-\mathrm{NHCOCH}_3, -\mathrm{COR},-\mathrm{OH},-\mathrm{COOH},-\mathrm{Cl}$$

The number of electrons present in all the completely filled subshells having $$\mathrm{n}=4$$ and $$\mathrm{s}=+\frac{1}{2}$$ is _______.

(Where $$\mathrm{n}=$$ principal quantum number and $$\mathrm{s}=$$ spin quantum number)

Sum of bond order of CO and NO$$^+$$ is ________.

From the given list, the number of compounds with +4 oxidation state of Sulphur ________.

$$\mathrm{SO}_3, \mathrm{H}_2 \mathrm{SO}_3, \mathrm{SOCl}_2, \mathrm{SF}_4, \mathrm{BaSO}_4, \mathrm{H}_2 \mathrm{S}_2 \mathrm{O}_7 $$

Mathematics

If $\int\limits_0^1 \frac{1}{\sqrt{3+x}+\sqrt{1+x}} \mathrm{~d} x=\mathrm{a}+\mathrm{b} \sqrt{2}+\mathrm{c} \sqrt{3}$, where $\mathrm{a}, \mathrm{b}, \mathrm{c}$ are rational numbers, then $2 \mathrm{a}+3 \mathrm{~b}-4 \mathrm{c}$ is equal to :

If $S=\{z \in C:|z-i|=|z+i|=|z-1|\}$, then, $n(S)$ is :

Let $S=\{1,2,3, \ldots, 10\}$. Suppose $M$ is the set of all the subsets of $S$, then the relation

$\mathrm{R}=\{(\mathrm{A}, \mathrm{B}): \mathrm{A} \cap \mathrm{B} \neq \phi ; \mathrm{A}, \mathrm{B} \in \mathrm{M}\}$ is :

If the shortest distance of the parabola $y^2=4 x$ from the centre of the circle $x^2+y^2-4 x-16 y+64=0$ is $\mathrm{d}$, then $\mathrm{d}^2$ is equal to :

If $(a, b)$ be the orthocentre of the triangle whose vertices are $(1,2),(2,3)$ and $(3,1)$, and $\mathrm{I}_1=\int\limits_{\mathrm{a}}^{\mathrm{b}} x \sin \left(4 x-x^2\right) \mathrm{d} x, \mathrm{I}_2=\int\limits_{\mathrm{a}}^{\mathrm{b}} \sin \left(4 x-x^2\right) \mathrm{d} x$, then $36 \frac{\mathrm{I}_1}{\mathrm{I}_2}$ is equal to :

Let $x=x(\mathrm{t})$ and $y=y(\mathrm{t})$ be solutions of the differential equations $\frac{\mathrm{d} x}{\mathrm{dt}}+\mathrm{a} x=0$ and $\frac{\mathrm{d} y}{\mathrm{dt}}+\mathrm{by}=0$ respectively, $\mathrm{a}, \mathrm{b} \in \mathbf{R}$. Given that $x(0)=2 ; y(0)=1$ and $3 y(1)=2 x(1)$, the value of $\mathrm{t}$, for which $x(\mathrm{t})=y(\mathrm{t})$, is :

The distance, of the point $(7,-2,11)$ from the line

$\frac{x-6}{1}=\frac{y-4}{0}=\frac{z-8}{3}$ along the line $\frac{x-5}{2}=\frac{y-1}{-3}=\frac{z-5}{6}$, is :

The length of the chord of the ellipse $\frac{x^2}{25}+\frac{y^2}{16}=1$, whose mid point is $\left(1, \frac{2}{5}\right)$, is equal to :

Consider the function.

$$ f(x)=\left\{\begin{array}{cc} \frac{\mathrm{a}\left(7 x-12-x^2\right)}{\mathrm{b}\left|x^2-7 x+12\right|} & , x<3 \\\\ 2^{\frac{\sin (x-3)}{x-[x]}} & , x>3 \\\\ \mathrm{~b} & , x=3, \end{array}\right. $$

where $[x]$ denotes the greatest integer less than or equal to $x$. If $\mathrm{S}$ denotes the set of all ordered pairs (a, b) such that $f(x)$ is continuous at $x=3$, then the number of elements in $\mathrm{S}$ is :

If $\mathrm{a}=\lim\limits_{x \rightarrow 0} \frac{\sqrt{1+\sqrt{1+x^4}}-\sqrt{2}}{x^4}$ and $\mathrm{b}=\lim\limits _{x \rightarrow 0} \frac{\sin ^2 x}{\sqrt{2}-\sqrt{1+\cos x}}$, then the value of $a b^3$ is :

Consider the matrix $f(x)=\left[\begin{array}{ccc}\cos x & -\sin x & 0 \\ \sin x & \cos x & 0 \\ 0 & 0 & 1\end{array}\right]$.

Given below are two statements :

Statement I : $ f(-x)$ is the inverse of the matrix $f(x)$.

Statement II : $f(x) f(y)=f(x+y)$.

In the light of the above statements, choose the correct answer from the options given below :

Four distinct points $(2 k, 3 k),(1,0),(0,1)$ and $(0,0)$ lie on a circle for $k$ equal to :

If the shortest distance between the lines

$\frac{x-4}{1}=\frac{y+1}{2}=\frac{z}{-3}$ and $\frac{x-\lambda}{2}=\frac{y+1}{4}=\frac{z-2}{-5}$ is $\frac{6}{\sqrt{5}}$, then the sum of all possible values of $\lambda$ is :

The portion of the line $4 x+5 y=20$ in the first quadrant is trisected by the lines $\mathrm{L}_1$ and $\mathrm{L}_2$ passing through the origin. The tangent of an angle between the lines $\mathrm{L}_1$ and $\mathrm{L}_2$ is :

${ }^{n-1} C_r=\left(k^2-8\right){ }^n C_{r+1}$ if and only if :

The number of common terms in the progressions

$4,9,14,19, \ldots \ldots$, up to $25^{\text {th }}$ term and

$3,6,9,12, \ldots \ldots$, up to $37^{\text {th }}$ term is :

Let $\mathrm{a}_1, \mathrm{a}_2, \ldots \mathrm{a}_{10}$ be 10 observations such that $\sum\limits_{\mathrm{k}=1}^{10} \mathrm{a}_{\mathrm{k}}=50$ and $\sum\limits_{\forall \mathrm{k} < \mathrm{j}} \mathrm{a}_{\mathrm{k}} \cdot \mathrm{a}_{\mathrm{j}}=1100$. Then the standard deviation of $\mathrm{a}_1, \mathrm{a}_2, \ldots, \mathrm{a}_{10}$ is equal to :

Let $\overrightarrow{\mathrm{a}}=\hat{i}+2 \hat{j}+\hat{k}, $
$\overrightarrow{\mathrm{b}}=3(\hat{i}-\hat{j}+\hat{k})$.
Let $\overrightarrow{\mathrm{c}}$ be the vector such that $\overrightarrow{\mathrm{a}} \times \overrightarrow{\mathrm{c}}=\overrightarrow{\mathrm{b}}$ and $\vec{a} \cdot \vec{c}=3$.
Then $\vec{a} \cdot((\vec{c} \times \vec{b})-\vec{b}-\vec{c})$ is equal to :

If A denotes the sum of all the coefficients in the expansion of $\left(1-3 x+10 x^2\right)^{\mathrm{n}}$ and B denotes the sum of all the coefficients in the expansion of $\left(1+x^2\right)^n$, then :

The function $f: \mathbf{N}-\{1\} \rightarrow \mathbf{N}$; defined by $f(\mathrm{n})=$ the highest prime factor of $\mathrm{n}$, is :

If $8=3+\frac{1}{4}(3+p)+\frac{1}{4^2}(3+2 p)+\frac{1}{4^3}(3+3 p)+\cdots \cdots \infty$, then the value of $p$ is ____________.

If the solution of the differential equation

$(2 x+3 y-2) \mathrm{d} x+(4 x+6 y-7) \mathrm{d} y=0, y(0)=3$, is

$\alpha x+\beta y+3 \log _e|2 x+3 y-\gamma|=6$, then $\alpha+2 \beta+3 \gamma$ is equal to ____________.

Let $f(x)=x^3+x^2 f^{\prime}(1)+x f^{\prime \prime}(2)+f^{\prime \prime \prime}(3), x \in \mathbf{R}$. Then $f^{\prime}(10)$ is equal to ____________.

Let the set of all $a \in \mathbf{R}$ such that the equation $\cos 2 x+a \sin x=2 a-7$ has a solution be $[p, q]$ and $r=\tan 9^{\circ}-\tan 27^{\circ}-\frac{1}{\cot 63^{\circ}}+\tan 81^{\circ}$, then pqr is equal to ____________.

Let for a differentiable function $f:(0, \infty) \rightarrow \mathbf{R}, f(x)-f(y) \geqslant \log _{\mathrm{e}}\left(\frac{x}{y}\right)+x-y, \forall x, y \in(0, \infty)$. Then $\sum\limits_{n=1}^{20} f^{\prime}\left(\frac{1}{n^2}\right)$ is equal to ____________.

Let the area of the region $\left\{(x, y): x-2 y+4 \geqslant 0, x+2 y^2 \geqslant 0, x+4 y^2 \leq 8, y \geqslant 0\right\}$ be $\frac{\mathrm{m}}{\mathrm{n}}$, where $\mathrm{m}$ and $\mathrm{n}$ are coprime numbers. Then $\mathrm{m}+\mathrm{n}$ is equal to _____________.

Let $A=\left[\begin{array}{lll}2 & 0 & 1 \\ 1 & 1 & 0 \\ 1 & 0 & 1\end{array}\right], B=\left[B_1, B_2, B_3\right]$, where $B_1, B_2, B_3$ are column matrics, and

$$ \mathrm{AB}_1=\left[\begin{array}{l} 1 \\ 0 \\ 0 \end{array}\right], \mathrm{AB}_2=\left[\begin{array}{l} 2 \\ 3 \\ 0 \end{array}\right], \quad \mathrm{AB}_3=\left[\begin{array}{l} 3 \\ 2 \\ 1 \end{array}\right] $$

If $\alpha=|B|$ and $\beta$ is the sum of all the diagonal elements of $B$, then $\alpha^3+\beta^3$ is equal to ____________.

The least positive integral value of $\alpha$, for which the angle between the vectors $\alpha \hat{i}-2 \hat{j}+2 \hat{k}$ and $\alpha \hat{i}+2 \alpha \hat{j}-2 \hat{k}$ is acute, is ___________.

If $\alpha$ satisfies the equation $x^2+x+1=0$ and $(1+\alpha)^7=A+B \alpha+C \alpha^2, A, B, C \geqslant 0$, then $5(3 A-2 B-C)$ is equal to ____________.

A fair die is tossed repeatedly until a six is obtained. Let $X$ denote the number of tosses required and let

$a=P(X=3), b=P(X \geqslant 3)$ and $c=P(X \geqslant 6 \mid X>3)$. Then $\frac{b+c}{a}$ is equal to __________.

Physics

Position of an ant ($$\mathrm{S}$$ in metres) moving in $$\mathrm{Y}$$-$$\mathrm{Z}$$ plane is given by $$S=2 t^2 \hat{j}+5 \hat{k}$$ (where $$t$$ is in second). The magnitude and direction of velocity of the ant at $$\mathrm{t}=1 \mathrm{~s}$$ will be :

Given below are two statements :

Statement (I) :Viscosity of gases is greater than that of liquids.

Statement (II) : Surface tension of a liquid decreases due to the presence of insoluble impurities.

In the light of the above statements, choose the most appropriate answer from the options given below :

If the refractive index of the material of a prism is $$\cot \left(\frac{A}{2}\right)$$, where $$A$$ is the angle of prism then the angle of minimum deviation will be

A proton moving with a constant velocity passes through a region of space without any change in its velocity. If $$\overrightarrow{\mathrm{E}}$$ and $$\overrightarrow{\mathrm{B}}$$ represent the electric and magnetic fields respectively, then the region of space may have :

(A) $$\mathrm{E}=0, \mathrm{~B}=0$$

(B) $$\mathrm{E}=0, \mathrm{~B} \neq 0$$

(D) $$\mathrm{E} \neq 0, \mathrm{~B} \neq 0$$

Choose the most appropriate answer from the options given below :

The acceleration due to gravity on the surface of earth is $$\mathrm{g}$$. If the diameter of earth reduces to half of its original value and mass remains constant, then acceleration due to gravity on the surface of earth would be :

A train is moving with a speed of $$12 \mathrm{~m} / \mathrm{s}$$ on rails which are $$1.5 \mathrm{~m}$$ apart. To negotiate a curve radius $$400 \mathrm{~m}$$, the height by which the outer rail should be raised with respect to the inner rail is (Given, $$g=10 \mathrm{~m} / \mathrm{s}^2)$$ :

Which of the following circuits is reverse - biased?

Identify the physical quantity that cannot be measured using spherometer :

Two bodies of mass $$4 \mathrm{~g}$$ and $$25 \mathrm{~g}$$ are moving with equal kinetic energies. The ratio of magnitude of their linear momentum is :

$$0.08 \mathrm{~kg}$$ air is heated at constant volume through $$5^{\circ} \mathrm{C}$$. The specific heat of air at constant volume is $$0.17 \mathrm{~kcal} / \mathrm{kg}^{\circ} \mathrm{C}$$ and $$\mathrm{J}=4.18$$ joule/$$\mathrm{~cal}$$. The change in its internal energy is approximately.

The radius of third stationary orbit of electron for Bohr's atom is R. The radius of fourth stationary orbit will be:

A rectangular loop of length $$2.5 \mathrm{~m}$$ and width $$2 \mathrm{~m}$$ is placed at $$60^{\circ}$$ to a magnetic field of $$4 \mathrm{~T}$$. The loop is removed from the field in $$10 \mathrm{~sec}$$. The average emf induced in the loop during this time is

An electric charge $$10^{-6} \mu \mathrm{C}$$ is placed at origin $$(0,0)$$ $$\mathrm{m}$$ of $$\mathrm{X}-\mathrm{Y}$$ co-ordinate system. Two points $$\mathrm{P}$$ and $$\mathrm{Q}$$ are situated at $$(\sqrt{3}, \sqrt{3}) \mathrm{m}$$ and $$(\sqrt{6}, 0) \mathrm{m}$$ respectively. The potential difference between the points $\mathrm{P}$ and $\mathrm{Q}$ will be :

A convex lens of focal length $$40 \mathrm{~cm}$$ forms an image of an extended source of light on a photoelectric cell. A current I is produced. The lens is replaced by another convex lens having the same diameter but focal length $$20 \mathrm{~cm}$$. The photoelectric current now is :

A body of mass $$1000 \mathrm{~kg}$$ is moving horizontally with a velocity $$6 \mathrm{~m} / \mathrm{s}$$. If $$200 \mathrm{~kg}$$ extra mass is added, the final velocity (in $$\mathrm{m} / \mathrm{s}$$) is:

A plane electromagnetic wave propagating in $$\mathrm{x}$$-direction is described by

$$E_y=\left(200 \mathrm{Vm}^{-1}\right) \sin \left[1.5 \times 10^7 t-0.05 x\right] \text {; }$$

The intensity of the wave is :

(Use $$\epsilon_0=8.85 \times 10^{-12} \mathrm{C}^2 \mathrm{~N}^{-1} \mathrm{~m}^{-2}$$)

Given below are two statements :

Statement (I) : Planck's constant and angular momentum have same dimensions.

Statement (II) : Linear momentum and moment of force have same dimensions.

In the light of the above statements, choose the correct answer from the options given below :

A wire of length $$10 \mathrm{~cm}$$ and radius $$\sqrt{7} \times 10^{-4} \mathrm{~m}$$ connected across the right gap of a meter bridge. When a resistance of $$4.5 \Omega$$ is connected on the left gap by using a resistance box, the balance length is found to be at $$60 \mathrm{~cm}$$ from the left end. If the resistivity of the wire is $$\mathrm{R} \times 10^{-7} \Omega \mathrm{m}$$, then value of $$\mathrm{R}$$ is :

A wire of resistance $$\mathrm{R}$$ and length $$\mathrm{L}$$ is cut into 5 equal parts. If these parts are joined parallely, then resultant resistance will be :

The average kinetic energy of a monatomic molecule is $$0.414 \mathrm{~eV}$$ at temperature :

(Use $$K_B=1.38 \times 10^{-23} \mathrm{~J} / \mathrm{mol}-\mathrm{K}$$)

A particle starts from origin at $$t=0$$ with a velocity $$5 \hat{i} \mathrm{~m} / \mathrm{s}$$ and moves in $$x-y$$ plane under action of a force which produces a constant acceleration of $$(3 \hat{i}+2 \hat{j}) \mathrm{m} / \mathrm{s}^2$$. If the $$x$$-coordinate of the particle at that instant is $$84 \mathrm{~m}$$, then the speed of the particle at this time is $$\sqrt{\alpha} \mathrm{~m} / \mathrm{s}$$. The value of $$\alpha$$ is _________.

A thin metallic wire having cross sectional area of $$10^{-4} \mathrm{~m}^2$$ is used to make a ring of radius $$30 \mathrm{~cm}$$. A positive charge of $$2 \pi \mathrm{~C}$$ is uniformly distributed over the ring, while another positive charge of 30 $$\mathrm{pC}$$ is kept at the centre of the ring. The tension in the ring is ______ $$\mathrm{N}$$; provided that the ring does not get deformed (neglect the influence of gravity). (given, $$\frac{1}{4 \pi \epsilon_0}=9 \times 10^9$$ SI units)

Two coils have mutual inductance $$0.002 \mathrm{~H}$$. The current changes in the first coil according to the relation $$\mathrm{i}=\mathrm{i}_0 \sin \omega \mathrm{t}$$, where $$\mathrm{i}_0=5 \mathrm{~A}$$ and $$\omega=50 \pi$$ rad/s. The maximum value of emf in the second coil is $$\frac{\pi}{\alpha} \mathrm{~V}$$. The value of $$\alpha$$ is _______.

Two immiscible liquids of refractive indices $$\frac{8}{5}$$ and $$\frac{3}{2}$$ respectively are put in a beaker as shown in the figure. The height of each column is $$6 \mathrm{~cm}$$. A coin is placed at the bottom of the beaker. For near normal vision, the apparent depth of the coin is $$\frac{\alpha}{4} \mathrm{~cm}$$. The value of $$\alpha$$ is _________.

In a nuclear fission process, a high mass nuclide $$(A \approx 236)$$ with binding energy $$7.6 \mathrm{~MeV} /$$ Nucleon dissociated into middle mass nuclides $$(\mathrm{A} \approx 118)$$, having binding energy of $$8.6 \mathrm{~MeV} / \mathrm{Nucleon}$$. The energy released in the process would be ______ $$\mathrm{MeV}$$.

Four particles each of mass $$1 \mathrm{~kg}$$ are placed at four corners of a square of side $$2 \mathrm{~m}$$. Moment of inertia of system about an axis perpendicular to its plane and passing through one of its vertex is _____ $$\mathrm{kgm}^2$$.

A particle executes simple harmonic motion with an amplitude of $$4 \mathrm{~cm}$$. At the mean position, velocity of the particle is $$10 \mathrm{~cm} / \mathrm{s}$$. The distance of the particle from the mean position when its speed becomes $$5 \mathrm{~cm} / \mathrm{s}$$ is $$\sqrt{\alpha} \mathrm{~cm}$$, where $$\alpha=$$ ________.

Two long, straight wires carry equal currents in opposite directions as shown in figure. The separation between the wires is $$5.0 \mathrm{~cm}$$. The magnitude of the magnetic field at a point $$\mathrm{P}$$ midway between the wires is _______ $$\mu \mathrm{T}$$

(Given : $$\mu_0=4 \pi \times 10^{-7} \mathrm{TmA}^{-1}$$)

The charge accumulated on the capacitor connected in the following circuit is _______ $$\mu \mathrm{C}$$ (Given $$\mathrm{C}=150 \mu \mathrm{F})$$

If average depth of an ocean is $$4000 \mathrm{~m}$$ and the bulk modulus of water is $$2 \times 10^9 \mathrm{~Nm}^{-2}$$, then fractional compression $$\frac{\Delta V}{V}$$ of water at the bottom of ocean is $$\alpha \times 10^{-2}$$. The value of $$\alpha$$ is _______ (Given, $$\mathrm{g}=10 \mathrm{~ms}^{-2}, \rho=1000 \mathrm{~kg} \mathrm{~m}^{-3}$$)