The number of s-electrons present in an ion with 55 protons in its unipositive state is

Find out the major products from the following reactions.

What is the number of unpaired electron(s) in the highest occupied molecular orbital of the following species : $$\mathrm{{N_2};N_2^ + ;{O_2};O_2^ + }$$ ?

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Benzene is more stable than hypothetical cyclohexatriene

Reason R : The delocalised $$\pi$$ electron cloud is attracted more strongly by nuclei of carbon atoms.

In the light of the above statements, choose the correct answer from the options given below:

Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.

Given below are two statements :

In the light of the above statements, choose the correct answer from the options given below:

Choose the correct colour of the product for the following reaction.

Which one amongst the following are good oxidizing agents?

A. Sm$$^{2+}$$

B. Ce$$^{2+}$$

C. Ce$$^{4+}$$

D. Tb$$^{4+}$$

Choose the most appropriate answer from the options given below :

A student has studied the decomposition of a gas AB$$_3$$ at 25$$^\circ$$C. He obtained the following data.

The order of the reaction is

The hybridization and magnetic behaviour of cobalt ion in $$\mathrm{[Co(NH_3)_6]^{3+}}$$ complex, respectively is :

$$\mathrm{K_2Cr_2O_7}$$ paper acidified with dilute $$\mathrm{H_2SO_4}$$ turns green when exposed to :

Which will undergo deprotonation most readily in the basic medium?

Which of the following cannot be explained by crystal field theory?

Given below are two statements:

Statement I : Pure Aniline and other arylamines are usually colourless.

Statement II : Arylamines get coloured on storage due to atmospheric reduction.

In the light of the above statements, choose the most appropriate answer from the options given below :

Total number of tripeptides possible by mixing of valine and proline is ___________

One mole of an ideal monoatomic gas is subjected to changes as shown in the graph. The magnitude of the work done (by the system or on the system) is __________ J (nearest integer)

Given ; $$\log2=0.3$$

$$\ln10=2.3$$

Maximum number of isomeric monochloro derivatives which can be obtained from 2,2,5,5-tetramethylhexane by chlorination is _____________

Following figure shows spectrum of an ideal black body at four different temperatures. The number of correct statement/s from the following is ____________.

A. $$\mathrm{T_4 > T_3 > T_2 > T_1}$$

B. The black body consists of particles performing simple harmonic motion.

C. The peak of the spectrum shifts to shorter wavelength as temperature increases.

D. $${{{T_1}} \over {{v_1}}} = {{{T_2}} \over {{v_2}}} = {{{T_3}} \over {{v_3}}} \ne $$ constant

E. The given spectrum could be explained using quantisation of energy.

Sum of $$\pi$$-bonds present in peroxodisulphuric acid and pyrosulphuric acid is ___________

The number of units, which are used to express concentration of solutions from the following is _________

Mass percent, Mole, Mole fraction, Molarity, ppm, Molality

The total pressure observed by mixing two liquids A and B is 350 mm Hg when their mole fractions are 0.7 and 0.3 respectively.

The total pressure becomes 410 mm Hg if the mole fractions are changed to 0.2 and 0.8 respectively for A and B. The vapour pressure of pure A is __________ mm Hg. (Nearest integer)

Consider the liquids and solutions behave ideally.

If the pKa of lactic acid is 5, then the pH of 0.005 M calcium lactate solution at 25$$^\circ$$C is ___________ $$\times$$ 10$$^{-1}$$ (Nearest integer)

Let $$f(x)$$ be a function such that $$f(x+y)=f(x).f(y)$$ for all $$x,y\in \mathbb{N}$$. If $$f(1)=3$$ and $$\sum\limits_{k = 1}^n {f(k) = 3279} $$, then the value of n is

The number of real solutions of the equation $$3\left( {{x^2} + {1 \over {{x^2}}}} \right) - 2\left( {x + {1 \over x}} \right) + 5 = 0$$, is

The number of integers, greater than 7000 that can be formed, using the digits 3, 5, 6, 7, 8 without repetition is :

Let $$\overrightarrow \alpha = 4\widehat i + 3\widehat j + 5\widehat k$$ and $$\overrightarrow \beta = \widehat i + 2\widehat j - 4\widehat k$$. Let $${\overrightarrow \beta _1}$$ be parallel to $$\overrightarrow \alpha $$ and $${\overrightarrow \beta _2}$$ be perpendicular to $$\overrightarrow \alpha $$. If $$\overrightarrow \beta = {\overrightarrow \beta _1} + {\overrightarrow \beta _2}$$, then the value of $$5{\overrightarrow \beta _2}\,.\left( {\widehat i + \widehat j + \widehat k} \right)$$ is :

If the system of equations

$$x+2y+3z=3$$

$$4x+3y-4z=4$$

$$8x+4y-\lambda z=9+\mu$$

has infinitely many solutions, then the ordered pair ($$\lambda,\mu$$) is equal to :

The set of all values of $$a$$ for which $$\mathop {\lim }\limits_{x \to a} ([x - 5] - [2x + 2]) = 0$$, where [$$\alpha$$] denotes the greatest integer less than or equal to $$\alpha$$ is equal to

The locus of the mid points of the chords of the circle $${C_1}:{(x - 4)^2} + {(y - 5)^2} = 4$$ which subtend an angle $${\theta _i}$$ at the centre of the circle $$C_1$$, is a circle of radius $$r_i$$. If $${\theta _1} = {\pi \over 3},{\theta _3} = {{2\pi } \over 3}$$ and $$r_1^2 = r_2^2 + r_3^2$$, then $${\theta _2}$$ is equal to :

Let $$y=y(x)$$ be the solution of the differential equation $$(x^2-3y^2)dx+3xy~dy=0,y(1)=1$$. Then $$6y^2(e)$$ is equal to

If $$f(x) = {{{2^{2x}}} \over {{2^{2x}} + 2}},x \in \mathbb{R}$$, then $$f\left( {{1 \over {2023}}} \right) + f\left( {{2 \over {2023}}} \right)\, + \,...\, + \,f\left( {{{2022} \over {2023}}} \right)$$ is equal to

The number of square matrices of order 5 with entries from the set {0, 1}, such that the sum of all the elements in each row is 1 and the sum of all the elements in each column is also 1, is :

Let the six numbers $$\mathrm{a_1,a_2,a_3,a_4,a_5,a_6}$$, be in A.P. and $$\mathrm{a_1+a_3=10}$$. If the mean of these six numbers is $$\frac{19}{2}$$ and their variance is $$\sigma^2$$, then 8$$\sigma^2$$ is equal to :

The value of $${\left( {{{1 + \sin {{2\pi } \over 9} + i\cos {{2\pi } \over 9}} \over {1 + \sin {{2\pi } \over 9} - i\cos {{2\pi } \over 9}}}} \right)^3}$$ is

If $$f(x) = {x^3} - {x^2}f'(1) + xf''(2) - f'''(3),x \in \mathbb{R}$$, then

$$\int\limits_{{{3\sqrt 2 } \over 4}}^{{{3\sqrt 3 } \over 4}} {{{48} \over {\sqrt {9 - 4{x^2}} }}dx} $$ is equal to :

The minimum number of elements that must be added to the relation R = {(a, b), (b, c), (b, d)} on the set {a, b, c, d} so that it is an equivalence relation, is __________.

If the shortest between the lines $${{x + \sqrt 6 } \over 2} = {{y - \sqrt 6 } \over 3} = {{z - \sqrt 6 } \over 4}$$ and $${{x - \lambda } \over 3} = {{y - 2\sqrt 6 } \over 4} = {{z + 2\sqrt 6 } \over 5}$$ is 6, then the square of sum of all possible values of $$\lambda$$ is :

Let $$\overrightarrow a = \widehat i + 2\widehat j + \lambda \widehat k,\overrightarrow b = 3\widehat i - 5\widehat j - \lambda \widehat k,\overrightarrow a \,.\,\overrightarrow c = 7,2\overrightarrow b \,.\,\overrightarrow c + 43 = 0,\overrightarrow a \times \overrightarrow c = \overrightarrow b \times \overrightarrow c $$. Then $$\left| {\overrightarrow a \,.\,\overrightarrow b } \right|$$ is equal to :

Let the sum of the coefficients of the first three terms in the expansion of $${\left( {x - {3 \over {{x^2}}}} \right)^n},x \ne 0.~n \in \mathbb{N}$$, be 376. Then the coefficient of $$x^4$$ is __________.

The equations of the sides AB, BC and CA of a triangle ABC are : $$2x+y=0,x+py=21a,(a\pm0)$$ and $$x-y=3$$ respectively. Let P(2, a) be the centroid of $$\Delta$$ABC. Then (BC)$$^2$$ is equal to ___________.

Let $$f$$ be $$a$$ differentiable function defined on $$\left[ {0,{\pi \over 2}} \right]$$ such that $$f(x) > 0$$ and $$f(x) + \int_0^x {f(t)\sqrt {1 - {{({{\log }_e}f(t))}^2}} dt = e,\forall x \in \left[ {0,{\pi \over 2}} \right]}$$. Then $$\left( {6{{\log }_e}f\left( {{\pi \over 6}} \right)} \right)^2$$ is equal to __________.

If the area of the region bounded by the curves $$y^2-2y=-x,x+y=0$$ is A, then 8 A is equal to __________

Three urns A, B and C contain 4 red, 6 black; 5 red, 5 black; and $$\lambda$$ red, 4 black balls respectively. One of the urns is selected at random and a ball is drawn. If the ball drawn is red and the probability that it is drawn from urn C is 0.4 then the square of the length of the side of the largest equilateral triangle, inscribed in the parabola $$y^2=\lambda x$$ with one vertex at the vertex of the parabola, is :

The logic gate equivalent to the given circuit diagram is :

The velocity time graph of a body moving in a straight line is shown in the figure.

The ratio of displacement to distance travelled by the body in time 0 to 10s is :

A long solenoid is formed by winding 70 turns cm$$^{-1}$$. If 2.0 A current flows, then the magnetic field produced inside the solenoid is ____________ ($$\mu_0=4\pi\times10^{-7}$$ TmA$$^{-1}$$)

A cell of emf 90 V is connected across series combination of two resistors each of 100$$\Omega$$ resistance. A voltmeter of resistance 400$$\Omega$$ is used to measure the potential difference across each resistor. The reading of the voltmeter will be :

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : A pendulum clock when taken to Mount Everest becomes fast.

Reason R : The value of g (acceleration due to gravity) is less at Mount Everest than its value on the surface of earth.

In the light of the above statements, choose the most appropriate answer from the options given below

Let $$\gamma_1$$ be the ratio of molar specific heat at constant pressure and molar specific heat at constant volume of a monoatomic gas and $$\gamma_2$$ be the similar ratio of diatomic gas. Considering the diatomic gas molecule as a rigid rotator, the ratio, $$\frac{\gamma_1}{\gamma_2}$$ is :

When a beam of white light is allowed to pass through convex lens parallel to principal axis, the different colours of light converge at different point on the principle axis after refraction. This is called :

In an Isothermal change, the change in pressure and volume of a gas can be represented for three different temperature; $$\mathrm{T_3 > T_2 > T_1}$$ as :

The electric field and magnetic field components of an electromagnetic wave going through vacuum is described by

$$\mathrm{{E_x} = {E_o}\sin (kz - \omega t)}$$

$$\mathrm{{B_y} = {B_o}\sin (kz - \omega t)}$$

Then the correct relation between E$$_0$$ and B$$_0$$ is given by

A metallic rod of length 'L' is rotated with an angular speed of '$$\omega$$' normal to a uniform magnetic field 'B' about an axis passing through one end of rod as shown in figure. The induced emf will be :

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Steel is used in the construction of buildings and bridges.

Reason R : Steel is more elastic and its elastic limit is high.

In the light of above statements, choose the most appropriate answer from the options given below

If the distance of the earth from Sun is 1.5 $$\times$$ 10$$^6$$ km. Then the distance of an imaginary planet from Sun, if its period of revolution is 2.83 years is :

The electric potential at the centre of two concentric half rings of radii R$$_1$$ and R$$_2$$, having same linear charge density $$\lambda$$ is :

Given below are two statements:

Statement I : Acceleration due to earth's gravity decreases as you go 'up' or 'down' from earth's surface.

Statement II : Acceleration due to earth's gravity is same at a height 'h' and depth 'd' from earth's surface, if h = d.

In the light of above statements, choose the most appropriate answer from the options given below

A photon is emitted in transition from n = 4 to n = 1 level in hydrogen atom. The corresponding wavelength for this transition is (given, h = 4 $$\times$$ 10$$^{-15}$$ eVs) :

The frequency ($$\nu$$) of an oscillating liquid drop may depend upon radius ($$r$$) of the drop, density ($$\rho$$) of liquid and the surface tension (s) of the liquid as $$\nu=r^a\rho^b s^c$$. The values of a, b and c respectively are

If two vectors $$\overrightarrow P = \widehat i + 2m\widehat j + m\widehat k$$ and $$\overrightarrow Q = 4\widehat i - 2\widehat j + m\widehat k$$ are perpendicular to each other. Then, the value of m will be :

A body of mass 200g is tied to a spring of spring constant 12.5 N/m, while the other end of spring is fixed at point O. If the body moves about O in a circular path on a smooth horizontal surface with constant angular speed 5 rad/s. Then the ratio of extension in the spring to its natural length will be :

A convex lens of refractive index 1.5 and focal length 18cm in air is immersed in water. The change in focal length of the lens will be ___________ cm.

(Given refractive index of water $$=\frac{4}{3}$$)

A body of mass 1kg begins to move under the action of a time dependent force $$\overrightarrow F = \left( {t\widehat i + 3{t^2}\,\widehat j} \right)$$ N, where $$\widehat i$$ and $$\widehat j$$ are the unit vectors along $$x$$ and $$y$$ axis. The power developed by above force, at the time t = 2s, will be ____________ W.

The energy released per fission of nucleus of $$^{240}$$X is 200 MeV. The energy released if all the atoms in 120g of pure $$^{240}$$X undergo fission is ____________ $$\times$$ 10$$^{25}$$ MeV.

(Given $$\mathrm{N_A=6\times10^{23}}$$)

A uniform solid cylinder with radius R and length L has moment of inertia I$$_1$$, about the axis of the cylinder. A concentric solid cylinder of radius $$R'=\frac{R}{2}$$ and length $$L'=\frac{L}{2}$$ is carved out of the original cylinder. If I$$_2$$ is the moment of inertia of the carved out portion of the cylinder then $$\frac{I_1}{I_2}=$$ __________.

(Both I$$_1$$ and I$$_2$$ are about the axis of the cylinder)

A parallel plate capacitor with air between the plate has a capacitance of 15pF. The separation between the plate becomes twice and the space between them is filled with a medium of dielectric constant 3.5. Then the capacitance becomes $$\frac{x}{4}$$ pF. The value of $$x$$ is ____________.

A single turn current loop in the shape of a right angle triangle with sides 5 cm, 12 cm, 13 cm is carrying a current of 2 A. The loop is in a uniform magnetic field of magnitude 0.75 T whose direction is parallel to the current in the 13 cm side of the loop. The magnitude of the magnetic force on the 5 cm side will be $$\frac{x}{130}$$ N. The value of $$x$$ is ____________.

A Spherical ball of radius 1mm and density 10.5 g/cc is dropped in glycerine of coefficient of viscosity 9.8 poise and density 1.5 g/cc. Viscous force on the ball when it attains constant velocity is $$3696\times10^{-x}$$ N. The value of $$x$$ is ________.

(Given, g = 9.8 m/s$$^2$$ and $$\pi=\frac{22}{7}$$)

A mass m attached to free end of a spring executes SHM with a period of 1s. If the mass is increased by 3 kg the period of the oscillation increases by one second, the value of mass m is ___________ kg.

Three identical resistors with resistance R = 12$$\Omega$$ and two identical inductors with self inductance L = 5 mH are connected to an ideal battery with emf of 12 V as shown in figure. The current through the battery long after the switch has been closed will be _____________ A.