The one that can exhibit highest paramagnetic behaviour among the following is :

gly = glycinato; bpy = 2, 2'-bipyridine

The Crystal Field Stabilization Energy
(CFSE) of [CoF₃(H₂O)₃] ($$\Delta $$₀ < P) is :

The process that is NOT endothermic in nature is :

The incorrect statement(s) among (a) - (c) is (are)

(a) W(VI) is more stable than Cr(VI).

(b) In the presence of HCl, permanganate titrations provide satisfactory results.

(c) Some lanthanoid oxides can be used as phosphors.

Among the following compounds, which one has the shortest C – Cl bond?

In the following reaction sequence, [C] is :

The number of chiral centres present in threonine is ________.

A 100 mL solution was made by adding 1.43 g of Na₂CO₃.xH₂O. The normality of the solution is 0.1 N. The value of x is _____.

(The atomic mass of Na is 23 g/mol)

The number of molecules with energy greater than the threshold energy for a reaction increases five fold by a rise of temperature from 27^oC to 42^oC. Its energy of activation in J/mol is _____.
(Take ln 5 = 1.6094; R = 8.314 J mol^–1 K^–1)

Consider the following equations :
2Fe²⁺ + H₂O₂ $$ \to $$ xA + yB
(in basic medium)
2MnO₄^- + 6H⁺ + 5H₂O₂ $$ \to $$ x'C + y'D + z'E
(in acidic medium)
The sum of the stoichiometric coefficients x, y, x', y', and z' for products A, B, C, D and E, respectively, is ______.

The osmotic pressure of a solution of NaCl is 0.10 atm and that of a glucose solution is 0.20 atm. The osmotic pressure of a solution formed by mixing 1 L of the sodium chloride solution with 2 L of
the glucose solution is x $$ \times $$ 10^–3 atm. x is _____. (nearest integer)

Which of the following compounds will form the precipitate with aq. AgNO₃ solution most readily?

The major product [R] in the following sequence of reactions as :

The molecule in which hybrid MOs involve only one d-orbital of the central atom is :

The major product [C] of the following reaction sequence will be :

The major product [B] in the following reactions is :

250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO₃ and 0.1 M AuCl. The solution was electrolyzed at 2V by passing a current of 1A for 15 minutes. The metal/metals electrodeposited will be

[ $$E_{A{g^ + }/Ag}^0$$ = 0.80 V, $$E_{A{u^ + }/Au}^0$$ = 1.69 V ]

Five moles of an ideal gas at 1 bar and 298 K is expanded into vacuum to double the volume. The work done is :

The shortest wavelength of H atom in the Lyman series is $$\lambda $$₁. The longest wavelength in the Balmar series of He⁺ is :

If the equilibrium constant for
A ⇌ B + C is $$K_{eq}^{(1)}$$ and that of
B + C ⇌ P is $$K_{eq}^{(2)}$$, the equilibrium
constant for A ⇌ P is :

The reaction in which the hybridisation of the underlined atom is affected is :

A test consists of 6 multiple choice questions, each having 4 alternative answers of which only one is correct. The number of ways, in which a candidate answers all six questions such that exactly four of the answers are correct, is __________.

If the variance of the following frequency distribution :

Class         : 10–20 20–30 30–40

Frequency :    2          x          2

is 50, then x is equal to____

If the system of equations
x+y+z=2
2x+4y–z=6
3x+2y+$$\lambda $$z=$$\mu $$
has infinitely many solutions, then

The integral
$$\int\limits_{{\pi \over 6}}^{{\pi \over 3}} {{{\tan }^3}x.{{\sin }^2}3x\left( {2{{\sec }^2}x.{{\sin }^2}3x + 3\tan x.\sin 6x} \right)dx} $$
is equal to:

In a game two players A and B take turns in throwing a pair of fair dice starting with player A and total of scores on the two dice, in each throw is noted. A wins the game if he throws total a of 6 before B throws a total of 7 and B wins the game if he throws a total of 7 before A throws a total of six. The game stops as soon as either of the players wins. The probability of A winning the game is :

The area (in sq. units) of the largest rectangle ABCD whose vertices A and B lie on the x-axis and vertices C and D lie on the parabola, y = x²–1 below the x-axis, is :

The minimum value of 2^sinx + 2^cosx is :

Let $$f:\left( {0,\infty } \right) \to \left( {0,\infty } \right)$$ be a differentiable function such that f(1) = e and
$$\mathop {\lim }\limits_{t \to x} {{{t^2}{f^2}(x) - {x^2}{f^2}(t)} \over {t - x}} = 0$$. If f(x) = 1, then x is equal to :

If the perpendicular bisector of the line segment joining the points P(1 ,4) and Q(k, 3) has y-intercept equal to –4, then a value of k is :

If a and b are real numbers such that
$${\left( {2 + \alpha } \right)^4} = a + b\alpha $$
where $$\alpha = {{ - 1 + i\sqrt 3 } \over 2}$$ then a + b is equal to :

Suppose the vectors x₁, x₂ and x₃ are the
solutions of the system of linear equations,
Ax = b when the vector b on the right side is equal to b₁, b₂ and b₃ respectively. if

$${x_1} = \left[ {\matrix{ 1 \cr 1 \cr 1 \cr } } \right]$$, $${x_2} = \left[ {\matrix{ 0 \cr 2 \cr 1 \cr } } \right]$$, $${x_3} = \left[ {\matrix{ 0 \cr 0 \cr 1 \cr } } \right]$$

$${b_1} = \left[ {\matrix{ 1 \cr 0 \cr 0 \cr } } \right]$$, $${b_2} = \left[ {\matrix{ 0 \cr 2 \cr 0 \cr } } \right]$$ and $${b_3} = \left[ {\matrix{ 0 \cr 0 \cr 2 \cr } } \right]$$,
then the determinant of A is equal to :

If $$\overrightarrow a = 2\widehat i + \widehat j + 2\widehat k$$, then the value of

$${\left| {\widehat i \times \left( {\overrightarrow a \times \widehat i} \right)} \right|^2} + {\left| {\widehat j \times \left( {\overrightarrow a \times \widehat j} \right)} \right|^2} + {\left| {\widehat k \times \left( {\overrightarrow a \times \widehat k} \right)} \right|^2}$$ is equal to____

Let PQ be a diameter of the circle x² + y² = 9. If $$\alpha $$ and $$\beta $$ are the lengths of the perpendiculars from P and Q on the straight line,
x + y = 2 respectively, then the maximum value of $$\alpha\beta $$ is _____.

Let {x} and [x] denote the fractional part of x and
the greatest integer $$ \le $$ x respectively of a real
number x. If $$\int_0^n {\left\{ x \right\}dx} ,\int_0^n {\left[ x \right]dx} $$ and 10(n² – n),
$$\left( {n \in N,n > 1} \right)$$ are three consecutive terms of a G.P., then n is equal to_____.

Let a₁, a₂, ..., an be a given A.P. whose
common difference is an integer and
S_n = a₁ + a₂ + .... + a_n. If a₁ = 1, a_n = 300 and 15 $$ \le $$ n $$ \le $$ 50, then
the ordered pair (S_n-4, a_n–4) is equal to:

Let $$\mathop \cup \limits_{i = 1}^{50} {X_i} = \mathop \cup \limits_{i = 1}^n {Y_i} = T$$ where each X_i contains 10 elements and each Y_i contains 5 elements. If each element of the set T is an element of exactly 20 of sets X_i’s and exactly 6 of sets Y_i’s, then n is equal to :

The solution of the differential equation

$${{dy} \over {dx}} - {{y + 3x} \over {{{\log }_e}\left( {y + 3x} \right)}} + 3 = 0$$ is:

(where c is a constant of integration)

The function
$$f(x) = \left\{ {\matrix{ {{\pi \over 4} + {{\tan }^{ - 1}}x,} & {\left| x \right| \le 1} \cr {{1 \over 2}\left( {\left| x \right| - 1} \right),} & {\left| x \right| > 1} \cr } } \right.$$ is :

The distance between an object and a screen is 100 cm. A lens can produce real image of the object on the screen for two different positions between the screen and the object. The distance between these two positions is 40 cm. If the power of the lens is close to $$\left( {{N \over {100}}} \right)D$$ where N is an integer, the value of N is _________.

The change in the magnitude of the volume of an ideal gas when a small additional pressure $$\Delta $$P is applied at a constant temperature, is the same as the change when the temperature is reduced by a small quantity $$\Delta $$T at constant pressure. The initial temperature and pressure of the gas were 300 K and 2 atm. respectively.
If |$$\Delta $$T| = C|$$\Delta $$P| then value of C in (K/atm.) is _________.

Orange light of wavelength 6000 $$ \times $$ 10^–10 m illuminates a single
slit of width 0.6 $$ \times $$ 10^–4 m. The maximum possible number of diffraction minima produced on both sides of the central maximum is ___________.

Two identical cylindrical vessels are kept on the ground and each contain the same liquid of density d. The area of the base of both vessels is S but the height of liquid in one vessel is x₁ and in the other, x₂ . When both cylinders are connected through a pipe of negligible volume very close to the bottom, the liquid flows from one vessel to the other until it comes to equilibrium at a new height. The change in energy of the system in the process is:

The value of current i₁ flowing from A to C in the circuit diagram is :

In a photoelectric effect experiment, the graph of stopping potential V versus reciprocal of wavelength obtained is shown in the figure. As the intensity of incident radiation is increased :

For a uniform rectangular sheet shown in the figure, the ratio of moments of inertia about the axes perpendicular to the sheet and passing through O (the centre of mass) and O' (corner point) is :

Four resistances 40 $$\Omega $$, 60 $$\Omega $$, 90 $$\Omega $$ and 110 $$\Omega $$ make the arms of a quadrilateral ABCD. Across AC is a battery of emf 40 V and internal resistance negligible.The potential difference across BD in V is _______.

A quantity x is given by $$\left( {{{IF{v^2}} \over {W{L^4}}}} \right)$$ in terms of moment of inertia I, force F, velocity v, work W and Length L. The dimensional formula for x is same as that of :

The speed verses time graph for a particle is shown in the figure. The distance travelled (in m) by the particle during the time interval t = 0 to t = 5 s will be________.

Identify the operation performed by the circuit given below :

A person pushes a box on a rough horizontal plateform surface. He applies a force of 200 N over a distance of 15 m. Thereafter, he gets progressively tired and his applied force reduces linearly with distance to 100 N. The total distance through which the box has been moved is 30 m. What is the work done by the person during the total movement of the box?

A cube of metal is subjected to a hydrostatic pressure of 4 GPa. The percentage change in the length of the side of the cube is close to :
(Given bulk modulus of metal, B = 8 $$ \times $$ 10¹⁰ Pa)

The electric field of a plane electromagnetic wave is given by
$$\overrightarrow E = {E_0}\left( {\widehat x + \widehat y} \right)\sin \left( {kz - \omega t} \right)$$
Its magnetic field will be given by :

Consider two uniform discs of the same thickness and different radii R₁ = R and
R₂ = $$\alpha $$R made of the same material. If the ratio of their moments of inertia I₁ and I₂ , respectively, about their axes is I₁ : I₂ = 1 : 16 then the value of $$\alpha $$ is :

A series L-R circuit is connected to a battery of emf V. If the circuit is switched on at t = 0, then the time at which the energy stored in the inductor reaches $$\left( {{1 \over n}} \right)$$ times of its maximum value, is :

Match the thermodynamic processes taking place in a system with the correct conditions. In the table : $$\Delta $$Q is the heat supplied, $$\Delta $$W is the work done and $$\Delta $$U is change in internal energy of the system.

Process	Condition
(I) Adiabatic	(1) $$\Delta $$W = 0
(II) Isothermal	(2) $$\Delta $$Q = 0
(III) Isochoric	(3) $$\Delta $$U $$ \ne $$ 0, $$\Delta $$W $$ \ne $$ 0, $$\Delta $$Q $$ \ne $$ 0
(IV) Isobaric	(4) $$\Delta $$U = 0

A small ball of mass m is thrown upward with velocity u from the ground. The ball experiences a resistive force mkv² where v is its speed. The maximum height attained by the ball is :

A circular coil has moment of inertia 0.8 kg m² around any diameter and is carrying current to produce a magnetic moment of 20 Am² . The coil is kept initially in a vertical position and it can rotate freely around a horizontal diameter. When a uniform magnetic field of 4 T is applied along the vertical,it starts rotating around its horizontal diameter. The angular speed the coil acquires after rotating by 60^o will be:

A particle of charge q and mass m is subjected to an electric field
E = E₀ (1 – $$a$$x²) in the x-direction, where $$a$$ and E₀ are constants. Initially the particle was at rest at x = 0. Other than the initial position the kinetic energy of the particle becomes zero when the distance of the particle from the origin is :

Find the Binding energy per neucleon for $${}_{50}^{120}Sn$$. Mass of proton m_p = 1.00783 U, mass of neutron m_n = 1.00867 U and mass of tin nucleus m_Sn = 119.902199 U. (take 1U = 931 MeV)

A capacitor C is fully charged with voltage V₀. After disconnecting the voltage source, it is connected in parallel with another uncharged capacitor of capacitance $${C \over 2}$$. The energy loss in the process after the charge is distributed between the two capacitors is :

A body is moving in a low circular orbit about a planet of mass M and radius R. The radius of the orbit can be taken to be R itself. Then the ratio of the speed of this body in the orbit to the escape velocity from the planet is:

A paramagnetic sample shows a net magnetisation of 6 A/m when it is placed in an external magnetic field of 0.4 T at a temperature of 4 K. When the sample is placed in an external magnetic field of 0.3 T at a temperature of 24 K, then the magnetisation will be: