Organic Chemistry
Some Basic Concepts of Organic Chemistry
MCQ (Single Correct Answer)MCQ (Multiple Correct Answer)
Alcohol, Phenols and Ethers
MCQ (Single Correct Answer)
Aldehydes, Ketones and Carboxylic Acids
MCQ (Single Correct Answer)MCQ (Multiple Correct Answer)
Organic Compounds Containing Nitrogen
MCQ (Single Correct Answer)
Chemistry in Everyday Life
MCQ (Single Correct Answer)
1
AIPMT 2009
MCQ (Single Correct Answer)
+4
-1
Half-life period of a first order reaction is 1386 seconds. The specific rate constant of the reaction is
A
0.5 $$ \times $$ 10$$-$$2 s$$-$$1
B
0.5 $$ \times $$ 10$$-$$3 s$$-$$1
C
5.0 $$ \times $$ 10$$-$$2 s$$-$$1
D
5.0 $$ \times $$ 10$$-$$3 s$$-$$1.
2
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The bromination of acetone that occurs in acid solution is represented by this equation.
CH3COCH3(aq) + Br2(aq)  $$ \to $$
     CH3COCH2Br(aq) + H+(aq) + Br$$-$$(aq)
These kinetic data were obtained for given reaction concentrations.
Initial concentrations, M
[CH3COCH3 [Br2] [H+]
0.30 0.05 0.05
0.30 0.10 0.05
0.30 0.10 0.10
0.40 0.05 0.20

Initial rate, disappearance of Br2, Ms$$-$$1
5.7$$ \times $$10$$-$$5
5.7$$ \times $$10$$-$$5
1.2$$ \times $$10$$-$$4
3.1$$ \times $$10$$-$$4

Based on these data, the rate equation is
A
Rate = k[CH3COCH3][Br2][H+]2
B
Rate = k[CH3COCH3][Br2][H+]
C
Rate = k[CH3COCH3][H+]
D
Rate = k[CH3COCH3][Br2]
3
AIPMT 2008
MCQ (Single Correct Answer)
+4
-1
The rate constants k1 and k2 for two different reactions are 1016 $$ \cdot $$ e$$-$$2000/T and 1015 $$ \cdot $$ e$$-$$1000/T, respectively.
The temperature at which k1 = k2 is
A
2000 K
B
$${{1000} \over {2.303}}K$$
C
1000 K
D
$${{2000} \over {2.303}}K$$
4
AIPMT 2007
MCQ (Single Correct Answer)
+4
-1
The reaction of hydrogen and iodine monochloride is given as :
H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g),
following mechanisms were proposed.

Mechanism A :
     H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
Mechanism B :
     H2(g) + ICl(g) $$ \to $$ HCl(g) + HI(g) ; slow
     HI(g) + ICl(g) $$ \to $$ HCl(g) + I2(g) ; fast

Which of the above mechanism(s) can be consistent with the given information about the reaction?
A
A and B both
B
Neither A nor B
C
A only
D
B only
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