If the molar conductivity $\left(\Lambda_{\mathrm{m}}\right)$ of a $0.050 \mathrm{~mol} \mathrm{~L}^{-1}$ solution of a monobasic weak acid is $90 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$, its extent (degree) of dissociation will be

[Assume $\Lambda_{+}^{\circ}=349.6 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ and $\Lambda_{-}^{\circ}=50.4 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$.]

Phosphoric acid ionizes in three steps with their ionization constant values $K_{a_1}, K_{a_2}$ and $K_{a_3}$, respectively, while $K$ is the overall ionization constant. Which of the following statements are true?

A. $\quad \log \mathrm{K}=\log \mathrm{K}_{\mathrm{a}_1}+\log \mathrm{K}_{\mathrm{a}_2}+\log \mathrm{K}_{\mathrm{a}_3}$

B. $\mathrm{H}_3 \mathrm{PO}_4$ is a stronger acid than $\mathrm{H}_2 \mathrm{PO}_4^{-}$and $\mathrm{HPO}_4^{2-}$

C. $K_{a_1}>K_{a_2}>K_{a_3}$

D. $K_{a_1}=\frac{K_{a_3}+K_{a_2}}{2}$

Choose the correct answer from the options given below :

Which indicator is used in the titration of sodium hydroxide against oxalic acid and what is the colour change at the end point?

The ratio of solubility of AgCl in 0.1 M KCl solution to the solubility of AgCl in water is:

(Given : Solubility product of AgCl = 10$$^{–10}$$)

An acidic buffer is prepared by mixing :

0.01 M acetic acid solution is 1% ionised, then pH of this acetic acid solution is :

The pH of the solution containing 50 mL each of 0.10 M sodium acetate and 0.01 M acetic acid is [Given pK_a of CH₃COOH = 4.57]